4-{2-[5-(3,5-Difluoro­phen­yl)-2-methyl­thio­phen-3-yl]-3,3,4,4,5,5-hexa­fluoro­cyclo­pent-1-en-1-yl}-1,5-dimethyl­pyrrole-2-carbonitrile

In the title compound, C(23)H(14)F(8)N(2)S, the dihedral angles between the pyrrole and thio­phene groups and the almost planar C—C=C—C unit of the cyclo­pentene ring (r.m.s. deviation = 0.4193 Å) are 43.6 (5) and 50.1 (2)°, respectively. The distance of 3.612 (3) Å between the potentially reactive...

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Detalles Bibliográficos
Autores principales: Liu, Gang, Wang, Xiao-mei, Fan, Cong-bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099757/
https://www.ncbi.nlm.nih.gov/pubmed/21754207
http://dx.doi.org/10.1107/S1600536811009780
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author Liu, Gang
Wang, Xiao-mei
Fan, Cong-bin
author_facet Liu, Gang
Wang, Xiao-mei
Fan, Cong-bin
author_sort Liu, Gang
collection PubMed
description In the title compound, C(23)H(14)F(8)N(2)S, the dihedral angles between the pyrrole and thio­phene groups and the almost planar C—C=C—C unit of the cyclo­pentene ring (r.m.s. deviation = 0.4193 Å) are 43.6 (5) and 50.1 (2)°, respectively. The distance of 3.612 (3) Å between the potentially reactive C atoms of the two heteroaryl substituents is short enough to enable a photocyclization reaction.
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spelling pubmed-30997572011-07-13 4-{2-[5-(3,5-Difluoro­phen­yl)-2-methyl­thio­phen-3-yl]-3,3,4,4,5,5-hexa­fluoro­cyclo­pent-1-en-1-yl}-1,5-dimethyl­pyrrole-2-carbonitrile Liu, Gang Wang, Xiao-mei Fan, Cong-bin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(14)F(8)N(2)S, the dihedral angles between the pyrrole and thio­phene groups and the almost planar C—C=C—C unit of the cyclo­pentene ring (r.m.s. deviation = 0.4193 Å) are 43.6 (5) and 50.1 (2)°, respectively. The distance of 3.612 (3) Å between the potentially reactive C atoms of the two heteroaryl substituents is short enough to enable a photocyclization reaction. International Union of Crystallography 2011-03-23 /pmc/articles/PMC3099757/ /pubmed/21754207 http://dx.doi.org/10.1107/S1600536811009780 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Gang
Wang, Xiao-mei
Fan, Cong-bin
4-{2-[5-(3,5-Difluoro­phen­yl)-2-methyl­thio­phen-3-yl]-3,3,4,4,5,5-hexa­fluoro­cyclo­pent-1-en-1-yl}-1,5-dimethyl­pyrrole-2-carbonitrile
title 4-{2-[5-(3,5-Difluoro­phen­yl)-2-methyl­thio­phen-3-yl]-3,3,4,4,5,5-hexa­fluoro­cyclo­pent-1-en-1-yl}-1,5-dimethyl­pyrrole-2-carbonitrile
title_full 4-{2-[5-(3,5-Difluoro­phen­yl)-2-methyl­thio­phen-3-yl]-3,3,4,4,5,5-hexa­fluoro­cyclo­pent-1-en-1-yl}-1,5-dimethyl­pyrrole-2-carbonitrile
title_fullStr 4-{2-[5-(3,5-Difluoro­phen­yl)-2-methyl­thio­phen-3-yl]-3,3,4,4,5,5-hexa­fluoro­cyclo­pent-1-en-1-yl}-1,5-dimethyl­pyrrole-2-carbonitrile
title_full_unstemmed 4-{2-[5-(3,5-Difluoro­phen­yl)-2-methyl­thio­phen-3-yl]-3,3,4,4,5,5-hexa­fluoro­cyclo­pent-1-en-1-yl}-1,5-dimethyl­pyrrole-2-carbonitrile
title_short 4-{2-[5-(3,5-Difluoro­phen­yl)-2-methyl­thio­phen-3-yl]-3,3,4,4,5,5-hexa­fluoro­cyclo­pent-1-en-1-yl}-1,5-dimethyl­pyrrole-2-carbonitrile
title_sort 4-{2-[5-(3,5-difluoro­phen­yl)-2-methyl­thio­phen-3-yl]-3,3,4,4,5,5-hexa­fluoro­cyclo­pent-1-en-1-yl}-1,5-dimethyl­pyrrole-2-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099757/
https://www.ncbi.nlm.nih.gov/pubmed/21754207
http://dx.doi.org/10.1107/S1600536811009780
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AT fancongbin 42535difluorophenyl2methylthiophen3yl334455hexafluorocyclopent1en1yl15dimethylpyrrole2carbonitrile

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