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Bis(2,4-dichloro­phen­oxy­acetato-κ(2) O (1),O (1′))(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)

In the title compound, [Co(C(8)H(5)Cl(2)O(3))(C(12)H(12)N(2))], the Co(II) atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichloro­phen­oxy­acetate ligands and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, displaying a distorted octa­hedral g...

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Detalles Bibliográficos
Autores principales: Ji, Li-Li, Liu, Jian-She, Song, Wen-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099758/
https://www.ncbi.nlm.nih.gov/pubmed/21754003
http://dx.doi.org/10.1107/S1600536811010579
Descripción
Sumario:In the title compound, [Co(C(8)H(5)Cl(2)O(3))(C(12)H(12)N(2))], the Co(II) atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichloro­phen­oxy­acetate ligands and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, displaying a distorted octa­hedral geometry. A three-dimensional supra­molecular structure is formed through inter­molecular C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine and benzene rings [centroid–centroid distance = 3.779 (2) Å].