Cargando…
Bis(2,4-dichlorophenoxyacetato-κ(2) O (1),O (1′))(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II)
In the title compound, [Co(C(8)H(5)Cl(2)O(3))(C(12)H(12)N(2))], the Co(II) atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichlorophenoxyacetate ligands and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, displaying a distorted octahedral g...
| Autores principales: | , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099758/ https://www.ncbi.nlm.nih.gov/pubmed/21754003 http://dx.doi.org/10.1107/S1600536811010579 |
| _version_ | 1782204077843677184 |
|---|---|
| author | Ji, Li-Li Liu, Jian-She Song, Wen-Dong |
| author_facet | Ji, Li-Li Liu, Jian-She Song, Wen-Dong |
| author_sort | Ji, Li-Li |
| collection | PubMed |
| description | In the title compound, [Co(C(8)H(5)Cl(2)O(3))(C(12)H(12)N(2))], the Co(II) atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichlorophenoxyacetate ligands and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, displaying a distorted octahedral geometry. A three-dimensional supramolecular structure is formed through intermolecular C—H⋯O hydrogen bonds and π–π stacking interactions between the pyridine and benzene rings [centroid–centroid distance = 3.779 (2) Å]. |
| format | Text |
| id | pubmed-3099758 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30997582011-07-13 Bis(2,4-dichlorophenoxyacetato-κ(2) O (1),O (1′))(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II) Ji, Li-Li Liu, Jian-She Song, Wen-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(8)H(5)Cl(2)O(3))(C(12)H(12)N(2))], the Co(II) atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichlorophenoxyacetate ligands and two N atoms from a 5,5′-dimethyl-2,2′-bipyridine ligand, displaying a distorted octahedral geometry. A three-dimensional supramolecular structure is formed through intermolecular C—H⋯O hydrogen bonds and π–π stacking interactions between the pyridine and benzene rings [centroid–centroid distance = 3.779 (2) Å]. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099758/ /pubmed/21754003 http://dx.doi.org/10.1107/S1600536811010579 Text en © Ji et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ji, Li-Li Liu, Jian-She Song, Wen-Dong Bis(2,4-dichlorophenoxyacetato-κ(2) O (1),O (1′))(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)cobalt(II) |
| title | Bis(2,4-dichlorophenoxyacetato-κ(2)
O
(1),O
(1′))(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cobalt(II) |
| title_full | Bis(2,4-dichlorophenoxyacetato-κ(2)
O
(1),O
(1′))(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cobalt(II) |
| title_fullStr | Bis(2,4-dichlorophenoxyacetato-κ(2)
O
(1),O
(1′))(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cobalt(II) |
| title_full_unstemmed | Bis(2,4-dichlorophenoxyacetato-κ(2)
O
(1),O
(1′))(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cobalt(II) |
| title_short | Bis(2,4-dichlorophenoxyacetato-κ(2)
O
(1),O
(1′))(5,5′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)cobalt(II) |
| title_sort | bis(2,4-dichlorophenoxyacetato-κ(2)
o
(1),o
(1′))(5,5′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099758/ https://www.ncbi.nlm.nih.gov/pubmed/21754003 http://dx.doi.org/10.1107/S1600536811010579 |
| work_keys_str_mv | AT jilili bis24dichlorophenoxyacetatok2o1o155dimethyl22bipyridinek2nncobaltii AT liujianshe bis24dichlorophenoxyacetatok2o1o155dimethyl22bipyridinek2nncobaltii AT songwendong bis24dichlorophenoxyacetatok2o1o155dimethyl22bipyridinek2nncobaltii |