catena-Poly[[zinc-bis­(μ-2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ato)-κ(2) O:S;κ(2) S:O] trihydrate]

In the title compound, {[Zn(C(8)H(5)N(2)O(2)S)(2)]·3H(2)O}(n), the Zn(II) atom, lying on a twofold rotation axis, is four-coordinated by two S atoms and two O atoms from four 2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ate (H(2)mbidc) ligands in a distorted tetra­hedral geometry. Two H(2)mbidc ligand...

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Detalles Bibliográficos
Autores principales: Li, Ya-Ping, Sun, Da-Jun, Zang, Hu, Han, Li-Ying, Su, Guan-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099766/
https://www.ncbi.nlm.nih.gov/pubmed/21753933
http://dx.doi.org/10.1107/S1600536811006532
Descripción
Sumario:In the title compound, {[Zn(C(8)H(5)N(2)O(2)S)(2)]·3H(2)O}(n), the Zn(II) atom, lying on a twofold rotation axis, is four-coordinated by two S atoms and two O atoms from four 2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ate (H(2)mbidc) ligands in a distorted tetra­hedral geometry. Two H(2)mbidc ligands bridge two Zn(II) atoms, generating a double-chain along [[Image: see text]01]. Adjacent chains are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. One of the two water molecules also lies on a twofold rotation axis.

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