catena-Poly[[zinc-bis­(μ-2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ato)-κ(2) O:S;κ(2) S:O] trihydrate]

In the title compound, {[Zn(C(8)H(5)N(2)O(2)S)(2)]·3H(2)O}(n), the Zn(II) atom, lying on a twofold rotation axis, is four-coordinated by two S atoms and two O atoms from four 2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ate (H(2)mbidc) ligands in a distorted tetra­hedral geometry. Two H(2)mbidc ligand...

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Detalles Bibliográficos
Autores principales: Li, Ya-Ping, Sun, Da-Jun, Zang, Hu, Han, Li-Ying, Su, Guan-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099766/
https://www.ncbi.nlm.nih.gov/pubmed/21753933
http://dx.doi.org/10.1107/S1600536811006532
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author Li, Ya-Ping
Sun, Da-Jun
Zang, Hu
Han, Li-Ying
Su, Guan-Fang
author_facet Li, Ya-Ping
Sun, Da-Jun
Zang, Hu
Han, Li-Ying
Su, Guan-Fang
author_sort Li, Ya-Ping
collection PubMed
description In the title compound, {[Zn(C(8)H(5)N(2)O(2)S)(2)]·3H(2)O}(n), the Zn(II) atom, lying on a twofold rotation axis, is four-coordinated by two S atoms and two O atoms from four 2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ate (H(2)mbidc) ligands in a distorted tetra­hedral geometry. Two H(2)mbidc ligands bridge two Zn(II) atoms, generating a double-chain along [[Image: see text]01]. Adjacent chains are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. One of the two water molecules also lies on a twofold rotation axis.
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spelling pubmed-30997662011-07-13 catena-Poly[[zinc-bis­(μ-2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ato)-κ(2) O:S;κ(2) S:O] trihydrate] Li, Ya-Ping Sun, Da-Jun Zang, Hu Han, Li-Ying Su, Guan-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(8)H(5)N(2)O(2)S)(2)]·3H(2)O}(n), the Zn(II) atom, lying on a twofold rotation axis, is four-coordinated by two S atoms and two O atoms from four 2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ate (H(2)mbidc) ligands in a distorted tetra­hedral geometry. Two H(2)mbidc ligands bridge two Zn(II) atoms, generating a double-chain along [[Image: see text]01]. Adjacent chains are linked by N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular network. One of the two water molecules also lies on a twofold rotation axis. International Union of Crystallography 2011-03-05 /pmc/articles/PMC3099766/ /pubmed/21753933 http://dx.doi.org/10.1107/S1600536811006532 Text en © Li et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Ya-Ping
Sun, Da-Jun
Zang, Hu
Han, Li-Ying
Su, Guan-Fang
catena-Poly[[zinc-bis­(μ-2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ato)-κ(2) O:S;κ(2) S:O] trihydrate]
title catena-Poly[[zinc-bis­(μ-2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ato)-κ(2) O:S;κ(2) S:O] trihydrate]
title_full catena-Poly[[zinc-bis­(μ-2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ato)-κ(2) O:S;κ(2) S:O] trihydrate]
title_fullStr catena-Poly[[zinc-bis­(μ-2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ato)-κ(2) O:S;κ(2) S:O] trihydrate]
title_full_unstemmed catena-Poly[[zinc-bis­(μ-2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ato)-κ(2) O:S;κ(2) S:O] trihydrate]
title_short catena-Poly[[zinc-bis­(μ-2-sulfido-1H-benzimidazol-3-ium-5-carboxyl­ato)-κ(2) O:S;κ(2) S:O] trihydrate]
title_sort catena-poly[[zinc-bis­(μ-2-sulfido-1h-benzimidazol-3-ium-5-carboxyl­ato)-κ(2) o:s;κ(2) s:o] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099766/
https://www.ncbi.nlm.nih.gov/pubmed/21753933
http://dx.doi.org/10.1107/S1600536811006532
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