(μ-Ethane-1,2-diamine-κ(2) N:N′)bis­[dicarbon­yl(η(5)-cyclo­penta­dien­yl)iron(II)] bis­(tetra­fluorido­borate)

The asymmetric unit of the title compound, [Fe(2)(C(5)H(5))(2)(C(2)H(8)N(2))(CO)(4)](BF(4))(2), contains two half-cations, each located on a center of symmetry, and two tetra­fluorido­borate anions. The iron atoms adopt a three-legged piano-stool geometry. All amine H atoms are involved in N—H⋯F hyd...

Descripción completa

Detalles Bibliográficos
Autores principales: M’thiruaine, Cyprian M., Friedrich, Holger B., Changamu, Evans O., Omondi, Bernard
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099767/
https://www.ncbi.nlm.nih.gov/pubmed/21753996
http://dx.doi.org/10.1107/S1600536811010154
Descripción
Sumario:The asymmetric unit of the title compound, [Fe(2)(C(5)H(5))(2)(C(2)H(8)N(2))(CO)(4)](BF(4))(2), contains two half-cations, each located on a center of symmetry, and two tetra­fluorido­borate anions. The iron atoms adopt a three-legged piano-stool geometry. All amine H atoms are involved in N—H⋯F hydrogen bonds, which consolidate the crystal packing along with weak C—H⋯O and C—H⋯F inter­actions.

Ejemplares similares