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(μ-Ethane-1,2-diamine-κ(2) N:N′)bis[dicarbonyl(η(5)-cyclopentadienyl)iron(II)] bis(tetrafluoridoborate)
The asymmetric unit of the title compound, [Fe(2)(C(5)H(5))(2)(C(2)H(8)N(2))(CO)(4)](BF(4))(2), contains two half-cations, each located on a center of symmetry, and two tetrafluoridoborate anions. The iron atoms adopt a three-legged piano-stool geometry. All amine H atoms are involved in N—H⋯F hyd...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099767/ https://www.ncbi.nlm.nih.gov/pubmed/21753996 http://dx.doi.org/10.1107/S1600536811010154 |
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| author | M’thiruaine, Cyprian M. Friedrich, Holger B. Changamu, Evans O. Omondi, Bernard |
| author_facet | M’thiruaine, Cyprian M. Friedrich, Holger B. Changamu, Evans O. Omondi, Bernard |
| author_sort | M’thiruaine, Cyprian M. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Fe(2)(C(5)H(5))(2)(C(2)H(8)N(2))(CO)(4)](BF(4))(2), contains two half-cations, each located on a center of symmetry, and two tetrafluoridoborate anions. The iron atoms adopt a three-legged piano-stool geometry. All amine H atoms are involved in N—H⋯F hydrogen bonds, which consolidate the crystal packing along with weak C—H⋯O and C—H⋯F interactions. |
| format | Text |
| id | pubmed-3099767 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30997672011-07-13 (μ-Ethane-1,2-diamine-κ(2) N:N′)bis[dicarbonyl(η(5)-cyclopentadienyl)iron(II)] bis(tetrafluoridoborate) M’thiruaine, Cyprian M. Friedrich, Holger B. Changamu, Evans O. Omondi, Bernard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Fe(2)(C(5)H(5))(2)(C(2)H(8)N(2))(CO)(4)](BF(4))(2), contains two half-cations, each located on a center of symmetry, and two tetrafluoridoborate anions. The iron atoms adopt a three-legged piano-stool geometry. All amine H atoms are involved in N—H⋯F hydrogen bonds, which consolidate the crystal packing along with weak C—H⋯O and C—H⋯F interactions. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099767/ /pubmed/21753996 http://dx.doi.org/10.1107/S1600536811010154 Text en © M'thiruaine et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers M’thiruaine, Cyprian M. Friedrich, Holger B. Changamu, Evans O. Omondi, Bernard (μ-Ethane-1,2-diamine-κ(2) N:N′)bis[dicarbonyl(η(5)-cyclopentadienyl)iron(II)] bis(tetrafluoridoborate) |
| title | (μ-Ethane-1,2-diamine-κ(2)
N:N′)bis[dicarbonyl(η(5)-cyclopentadienyl)iron(II)] bis(tetrafluoridoborate) |
| title_full | (μ-Ethane-1,2-diamine-κ(2)
N:N′)bis[dicarbonyl(η(5)-cyclopentadienyl)iron(II)] bis(tetrafluoridoborate) |
| title_fullStr | (μ-Ethane-1,2-diamine-κ(2)
N:N′)bis[dicarbonyl(η(5)-cyclopentadienyl)iron(II)] bis(tetrafluoridoborate) |
| title_full_unstemmed | (μ-Ethane-1,2-diamine-κ(2)
N:N′)bis[dicarbonyl(η(5)-cyclopentadienyl)iron(II)] bis(tetrafluoridoborate) |
| title_short | (μ-Ethane-1,2-diamine-κ(2)
N:N′)bis[dicarbonyl(η(5)-cyclopentadienyl)iron(II)] bis(tetrafluoridoborate) |
| title_sort | (μ-ethane-1,2-diamine-κ(2)
n:n′)bis[dicarbonyl(η(5)-cyclopentadienyl)iron(ii)] bis(tetrafluoridoborate) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099767/ https://www.ncbi.nlm.nih.gov/pubmed/21753996 http://dx.doi.org/10.1107/S1600536811010154 |
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