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Aqua{N,N-dimethyl-N′-[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)nickel(II)
In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N′,N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothiocyanate groups and one water molecule. In the crystal, O—H⋯S hydrogen bonds link adjacent molecules into infinite lay...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099768/ https://www.ncbi.nlm.nih.gov/pubmed/21754017 http://dx.doi.org/10.1107/S1600536811011512 |
Sumario: | In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N′,N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothiocyanate groups and one water molecule. In the crystal, O—H⋯S hydrogen bonds link adjacent molecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C—H⋯π interactions. The –CH(2)–N(CH(3))(2) fragment is disordered over two sets of sites in a 0.556 (5):0.444 (5) ratio. |
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