Aqua­{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)nickel(II)

In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N′,N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothio­cyanate groups and one water mol­ecule. In the crystal, O—H⋯S hydrogen bonds link adjacent mol­ecules into infinite lay...

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Autores principales: Suleiman Gwaram, Nura, Saharin, Siti Munirah, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099768/
https://www.ncbi.nlm.nih.gov/pubmed/21754017
http://dx.doi.org/10.1107/S1600536811011512
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author Suleiman Gwaram, Nura
Saharin, Siti Munirah
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Suleiman Gwaram, Nura
Saharin, Siti Munirah
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Suleiman Gwaram, Nura
collection PubMed
description In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N′,N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothio­cyanate groups and one water mol­ecule. In the crystal, O—H⋯S hydrogen bonds link adjacent mol­ecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C—H⋯π inter­actions. The –CH(2)–N(CH(3))(2) fragment is disordered over two sets of sites in a 0.556 (5):0.444 (5) ratio.
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spelling pubmed-30997682011-07-13 Aqua­{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)nickel(II) Suleiman Gwaram, Nura Saharin, Siti Munirah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(NCS)(2)(C(11)H(17)N(3))(H(2)O)], the Ni(II) ion is six-coordinated by the N,N′,N"-tridentate Schiff base N atoms, two cis-positioned N-bound isothio­cyanate groups and one water mol­ecule. In the crystal, O—H⋯S hydrogen bonds link adjacent mol­ecules into infinite layers parallel to the ac plane. The layers are further connected into a three-dimensional network via C—H⋯π inter­actions. The –CH(2)–N(CH(3))(2) fragment is disordered over two sets of sites in a 0.556 (5):0.444 (5) ratio. International Union of Crystallography 2011-03-31 /pmc/articles/PMC3099768/ /pubmed/21754017 http://dx.doi.org/10.1107/S1600536811011512 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suleiman Gwaram, Nura
Saharin, Siti Munirah
Khaledi, Hamid
Mohd Ali, Hapipah
Aqua­{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)nickel(II)
title Aqua­{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)nickel(II)
title_full Aqua­{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)nickel(II)
title_fullStr Aqua­{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)nickel(II)
title_full_unstemmed Aqua­{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)nickel(II)
title_short Aqua­{N,N-dimethyl-N′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)nickel(II)
title_sort aqua­{n,n-dimethyl-n′-[1-(2-pyrid­yl)ethyl­idene]ethane-1,2-diamine-κ(3) n,n′,n′′}bis­(thio­cyanato-κn)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099768/
https://www.ncbi.nlm.nih.gov/pubmed/21754017
http://dx.doi.org/10.1107/S1600536811011512
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