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Bis(3,5-dimethyl-1H-pyrazole-κN (2))silver(I) hexa­fluorido­anti­monate

The title compound, [Ag(C(5)H(8)N(2))(2)]SbF(6), contains an Ag(+) cation almost linearly bonded to two N atoms of dimethylpyrazole ligands [N—Ag—N = 176.54 (18)°]. The structure exhibits hydrogen bonding between the two dimethyl­pyrazole H atoms and two F atoms of one hexa­fluorido­anti­monate anio...

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Detalles Bibliográficos
Autores principales: Crawford, Devyn, Hofer, Anthony K., Edler, Kate L., Ferrence, Gregory M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099769/
https://www.ncbi.nlm.nih.gov/pubmed/21754005
http://dx.doi.org/10.1107/S1600536811010567
Descripción
Sumario:The title compound, [Ag(C(5)H(8)N(2))(2)]SbF(6), contains an Ag(+) cation almost linearly bonded to two N atoms of dimethylpyrazole ligands [N—Ag—N = 176.54 (18)°]. The structure exhibits hydrogen bonding between the two dimethyl­pyrazole H atoms and two F atoms of one hexa­fluorido­anti­monate anion. Three relatively short Ag⋯F contacts [2.869 (6), 2.920 (7), and 3.094 (7) Å] exist between the cation and three different SbF(6) (−) anions. The crystal used for data collection was found to be twinned by non-merohedry, with the two components being related by a 180° rotation around the real or reciprocal a axis. Integration resulted in 11.2% of the total peaks being assigned to component 1, 11.2% to component 2, and 77.6% to both components.