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Bis(3,5-dimethyl-1H-pyrazole-κN (2))silver(I) hexafluoridoantimonate
The title compound, [Ag(C(5)H(8)N(2))(2)]SbF(6), contains an Ag(+) cation almost linearly bonded to two N atoms of dimethylpyrazole ligands [N—Ag—N = 176.54 (18)°]. The structure exhibits hydrogen bonding between the two dimethylpyrazole H atoms and two F atoms of one hexafluoridoantimonate anio...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099769/ https://www.ncbi.nlm.nih.gov/pubmed/21754005 http://dx.doi.org/10.1107/S1600536811010567 |
Sumario: | The title compound, [Ag(C(5)H(8)N(2))(2)]SbF(6), contains an Ag(+) cation almost linearly bonded to two N atoms of dimethylpyrazole ligands [N—Ag—N = 176.54 (18)°]. The structure exhibits hydrogen bonding between the two dimethylpyrazole H atoms and two F atoms of one hexafluoridoantimonate anion. Three relatively short Ag⋯F contacts [2.869 (6), 2.920 (7), and 3.094 (7) Å] exist between the cation and three different SbF(6) (−) anions. The crystal used for data collection was found to be twinned by non-merohedry, with the two components being related by a 180° rotation around the real or reciprocal a axis. Integration resulted in 11.2% of the total peaks being assigned to component 1, 11.2% to component 2, and 77.6% to both components. |
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