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Bis(3,5-dimethyl-1H-pyrazole-κN (2))silver(I) hexa­fluorido­anti­monate

The title compound, [Ag(C(5)H(8)N(2))(2)]SbF(6), contains an Ag(+) cation almost linearly bonded to two N atoms of dimethylpyrazole ligands [N—Ag—N = 176.54 (18)°]. The structure exhibits hydrogen bonding between the two dimethyl­pyrazole H atoms and two F atoms of one hexa­fluorido­anti­monate anio...

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Detalles Bibliográficos
Autores principales: Crawford, Devyn, Hofer, Anthony K., Edler, Kate L., Ferrence, Gregory M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099769/
https://www.ncbi.nlm.nih.gov/pubmed/21754005
http://dx.doi.org/10.1107/S1600536811010567
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author Crawford, Devyn
Hofer, Anthony K.
Edler, Kate L.
Ferrence, Gregory M.
author_facet Crawford, Devyn
Hofer, Anthony K.
Edler, Kate L.
Ferrence, Gregory M.
author_sort Crawford, Devyn
collection PubMed
description The title compound, [Ag(C(5)H(8)N(2))(2)]SbF(6), contains an Ag(+) cation almost linearly bonded to two N atoms of dimethylpyrazole ligands [N—Ag—N = 176.54 (18)°]. The structure exhibits hydrogen bonding between the two dimethyl­pyrazole H atoms and two F atoms of one hexa­fluorido­anti­monate anion. Three relatively short Ag⋯F contacts [2.869 (6), 2.920 (7), and 3.094 (7) Å] exist between the cation and three different SbF(6) (−) anions. The crystal used for data collection was found to be twinned by non-merohedry, with the two components being related by a 180° rotation around the real or reciprocal a axis. Integration resulted in 11.2% of the total peaks being assigned to component 1, 11.2% to component 2, and 77.6% to both components.
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spelling pubmed-30997692011-07-13 Bis(3,5-dimethyl-1H-pyrazole-κN (2))silver(I) hexa­fluorido­anti­monate Crawford, Devyn Hofer, Anthony K. Edler, Kate L. Ferrence, Gregory M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ag(C(5)H(8)N(2))(2)]SbF(6), contains an Ag(+) cation almost linearly bonded to two N atoms of dimethylpyrazole ligands [N—Ag—N = 176.54 (18)°]. The structure exhibits hydrogen bonding between the two dimethyl­pyrazole H atoms and two F atoms of one hexa­fluorido­anti­monate anion. Three relatively short Ag⋯F contacts [2.869 (6), 2.920 (7), and 3.094 (7) Å] exist between the cation and three different SbF(6) (−) anions. The crystal used for data collection was found to be twinned by non-merohedry, with the two components being related by a 180° rotation around the real or reciprocal a axis. Integration resulted in 11.2% of the total peaks being assigned to component 1, 11.2% to component 2, and 77.6% to both components. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099769/ /pubmed/21754005 http://dx.doi.org/10.1107/S1600536811010567 Text en © Crawford et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Crawford, Devyn
Hofer, Anthony K.
Edler, Kate L.
Ferrence, Gregory M.
Bis(3,5-dimethyl-1H-pyrazole-κN (2))silver(I) hexa­fluorido­anti­monate
title Bis(3,5-dimethyl-1H-pyrazole-κN (2))silver(I) hexa­fluorido­anti­monate
title_full Bis(3,5-dimethyl-1H-pyrazole-κN (2))silver(I) hexa­fluorido­anti­monate
title_fullStr Bis(3,5-dimethyl-1H-pyrazole-κN (2))silver(I) hexa­fluorido­anti­monate
title_full_unstemmed Bis(3,5-dimethyl-1H-pyrazole-κN (2))silver(I) hexa­fluorido­anti­monate
title_short Bis(3,5-dimethyl-1H-pyrazole-κN (2))silver(I) hexa­fluorido­anti­monate
title_sort bis(3,5-dimethyl-1h-pyrazole-κn (2))silver(i) hexa­fluorido­anti­monate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099769/
https://www.ncbi.nlm.nih.gov/pubmed/21754005
http://dx.doi.org/10.1107/S1600536811010567
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