6,6′-Dieth­oxy-2,2′-[hexane-1,6-diylbis(nitrilo­methanylyl­idene)]diphenol

The title compound, C(24)H(32)N(2)O(4), is a polydentate Schiff base and reveals strong intra­molecular O—H⋯N hydrogen bonding between the hy­droxy O atom and the imino N atom, with an O⋯N distance of 2.570 (3) Å. In the crystal, a centre of inversion is located at the mid-point of the compound. The...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099770/
https://www.ncbi.nlm.nih.gov/pubmed/21754189
http://dx.doi.org/10.1107/S1600536811009445
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The title compound, C(24)H(32)N(2)O(4), is a polydentate Schiff base and reveals strong intra­molecular O—H⋯N hydrogen bonding between the hy­droxy O atom and the imino N atom, with an O⋯N distance of 2.570 (3) Å. In the crystal, a centre of inversion is located at the mid-point of the compound. The diimino­hexyl­ene chain is almost ideally in the anti conformation, with an average dihedral angle of 179.0°.
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spelling pubmed-30997702011-07-13 6,6′-Dieth­oxy-2,2′-[hexane-1,6-diylbis(nitrilo­methanylyl­idene)]diphenol Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(32)N(2)O(4), is a polydentate Schiff base and reveals strong intra­molecular O—H⋯N hydrogen bonding between the hy­droxy O atom and the imino N atom, with an O⋯N distance of 2.570 (3) Å. In the crystal, a centre of inversion is located at the mid-point of the compound. The diimino­hexyl­ene chain is almost ideally in the anti conformation, with an average dihedral angle of 179.0°. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3099770/ /pubmed/21754189 http://dx.doi.org/10.1107/S1600536811009445 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ha, Kwang
6,6′-Dieth­oxy-2,2′-[hexane-1,6-diylbis(nitrilo­methanylyl­idene)]diphenol
title 6,6′-Dieth­oxy-2,2′-[hexane-1,6-diylbis(nitrilo­methanylyl­idene)]diphenol
title_full 6,6′-Dieth­oxy-2,2′-[hexane-1,6-diylbis(nitrilo­methanylyl­idene)]diphenol
title_fullStr 6,6′-Dieth­oxy-2,2′-[hexane-1,6-diylbis(nitrilo­methanylyl­idene)]diphenol
title_full_unstemmed 6,6′-Dieth­oxy-2,2′-[hexane-1,6-diylbis(nitrilo­methanylyl­idene)]diphenol
title_short 6,6′-Dieth­oxy-2,2′-[hexane-1,6-diylbis(nitrilo­methanylyl­idene)]diphenol
title_sort 6,6′-dieth­oxy-2,2′-[hexane-1,6-diylbis(nitrilo­methanylyl­idene)]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099770/
https://www.ncbi.nlm.nih.gov/pubmed/21754189
http://dx.doi.org/10.1107/S1600536811009445
work_keys_str_mv AT hakwang 66diethoxy22hexane16diylbisnitrilomethanylylidenediphenol

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