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catena-Poly[[{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}(thiocyanato-κN)cadmium]-μ-thiocyanato-κ(2) S:N]
In the title compound, [Cd(NCS)(2)(C(11)H(17)N(3))](n), the Cd(II) atom is octahedrally coordinated by the N,N′,N′′-tridentate Schiff base ligand and one terminal thiocyanate N atom. Two trans-N:S-bridging thiocyanates complete the N(5)S donor set around the Cd atom. In the crystal, adjacent Cd(I...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099776/ https://www.ncbi.nlm.nih.gov/pubmed/21753992 http://dx.doi.org/10.1107/S1600536811010063 |
| _version_ | 1782204082058952704 |
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| author | Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah |
| author_facet | Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah |
| author_sort | Suleiman Gwaram, Nura |
| collection | PubMed |
| description | In the title compound, [Cd(NCS)(2)(C(11)H(17)N(3))](n), the Cd(II) atom is octahedrally coordinated by the N,N′,N′′-tridentate Schiff base ligand and one terminal thiocyanate N atom. Two trans-N:S-bridging thiocyanates complete the N(5)S donor set around the Cd atom. In the crystal, adjacent Cd(II) ions are linked by the thiocyanate N:S-bridges into polymeric chains along the c axis. |
| format | Text |
| id | pubmed-3099776 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30997762011-07-13 catena-Poly[[{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}(thiocyanato-κN)cadmium]-μ-thiocyanato-κ(2) S:N] Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(NCS)(2)(C(11)H(17)N(3))](n), the Cd(II) atom is octahedrally coordinated by the N,N′,N′′-tridentate Schiff base ligand and one terminal thiocyanate N atom. Two trans-N:S-bridging thiocyanates complete the N(5)S donor set around the Cd atom. In the crystal, adjacent Cd(II) ions are linked by the thiocyanate N:S-bridges into polymeric chains along the c axis. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099776/ /pubmed/21753992 http://dx.doi.org/10.1107/S1600536811010063 Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Suleiman Gwaram, Nura Khaledi, Hamid Mohd Ali, Hapipah catena-Poly[[{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3) N,N′,N′′}(thiocyanato-κN)cadmium]-μ-thiocyanato-κ(2) S:N] |
| title |
catena-Poly[[{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}(thiocyanato-κN)cadmium]-μ-thiocyanato-κ(2)
S:N] |
| title_full |
catena-Poly[[{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}(thiocyanato-κN)cadmium]-μ-thiocyanato-κ(2)
S:N] |
| title_fullStr |
catena-Poly[[{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}(thiocyanato-κN)cadmium]-μ-thiocyanato-κ(2)
S:N] |
| title_full_unstemmed |
catena-Poly[[{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}(thiocyanato-κN)cadmium]-μ-thiocyanato-κ(2)
S:N] |
| title_short |
catena-Poly[[{N,N-dimethyl-N′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
N,N′,N′′}(thiocyanato-κN)cadmium]-μ-thiocyanato-κ(2)
S:N] |
| title_sort | catena-poly[[{n,n-dimethyl-n′-[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ(3)
n,n′,n′′}(thiocyanato-κn)cadmium]-μ-thiocyanato-κ(2)
s:n] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099776/ https://www.ncbi.nlm.nih.gov/pubmed/21753992 http://dx.doi.org/10.1107/S1600536811010063 |
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