Bis[(2S,4S)-4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium] di-μ-chlorido-bis­[trichloridocadmium(II)]

The asymmetric unit of the title compound, (C(7)H(18)N(2)O)(2)[Cd(2)Cl(8)], comprises one 4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium dication and a half [Cd(2)Cl(8)](4−) anion. The two Cd atoms are each coordinated by two bridging Cl atoms and three terminal Cl atoms and the [Cd(2)Cl(8)](4−...

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Detalles Bibliográficos
Autor principal: Rong, Tao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099779/
https://www.ncbi.nlm.nih.gov/pubmed/21753932
http://dx.doi.org/10.1107/S1600536811006945
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author Rong, Tao
author_facet Rong, Tao
author_sort Rong, Tao
collection PubMed
description The asymmetric unit of the title compound, (C(7)H(18)N(2)O)(2)[Cd(2)Cl(8)], comprises one 4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium dication and a half [Cd(2)Cl(8)](4−) anion. The two Cd atoms are each coordinated by two bridging Cl atoms and three terminal Cl atoms and the [Cd(2)Cl(8)](4−) anion is located on an inversion centre. The crystal structure consists of N—H⋯Cl hydrogen-bonded sheets, which are further linked by C—H⋯Cl contacts, yielding a three-dimensional network.
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spelling pubmed-30997792011-07-13 Bis[(2S,4S)-4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium] di-μ-chlorido-bis­[trichloridocadmium(II)] Rong, Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(7)H(18)N(2)O)(2)[Cd(2)Cl(8)], comprises one 4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium dication and a half [Cd(2)Cl(8)](4−) anion. The two Cd atoms are each coordinated by two bridging Cl atoms and three terminal Cl atoms and the [Cd(2)Cl(8)](4−) anion is located on an inversion centre. The crystal structure consists of N—H⋯Cl hydrogen-bonded sheets, which are further linked by C—H⋯Cl contacts, yielding a three-dimensional network. International Union of Crystallography 2011-03-02 /pmc/articles/PMC3099779/ /pubmed/21753932 http://dx.doi.org/10.1107/S1600536811006945 Text en © Tao Rong 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rong, Tao
Bis[(2S,4S)-4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium] di-μ-chlorido-bis­[trichloridocadmium(II)]
title Bis[(2S,4S)-4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium] di-μ-chlorido-bis­[trichloridocadmium(II)]
title_full Bis[(2S,4S)-4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium] di-μ-chlorido-bis­[trichloridocadmium(II)]
title_fullStr Bis[(2S,4S)-4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium] di-μ-chlorido-bis­[trichloridocadmium(II)]
title_full_unstemmed Bis[(2S,4S)-4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium] di-μ-chlorido-bis­[trichloridocadmium(II)]
title_short Bis[(2S,4S)-4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium] di-μ-chlorido-bis­[trichloridocadmium(II)]
title_sort bis[(2s,4s)-4-(2-hy­droxy­eth­yl)-2-methyl­piperazine-1,4-diium] di-μ-chlorido-bis­[trichloridocadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099779/
https://www.ncbi.nlm.nih.gov/pubmed/21753932
http://dx.doi.org/10.1107/S1600536811006945
work_keys_str_mv AT rongtao bis2s4s42hydroxyethyl2methylpiperazine14diiumdimchloridobistrichloridocadmiumii

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