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cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ(2) N,N′]bis(dimethyl sulfoxide-κO)cadmium
The complete molecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethylsulfoxide molecules. The resulting N(4)O(2) donor set disp...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099781/ https://www.ncbi.nlm.nih.gov/pubmed/21754012 http://dx.doi.org/10.1107/S1600536811010816 |
Sumario: | The complete molecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethylsulfoxide molecules. The resulting N(4)O(2) donor set displays a distorted trigonal–prismatic coordination geometry. The S atom and methyl groups of dimethylsulfoxide are disordered over two sets of sites, with site occupancies of 0.715 (4) and 0.285 (4). The crystal structure features intermolecular N—H⋯N and N—H⋯O hydrogen bonds that lead to the formation of layers in the ab plane. |
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