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cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ(2) N,N′]bis(dimethyl sulfoxide-κO)cadmium
The complete molecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethylsulfoxide molecules. The resulting N(4)O(2) donor set disp...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099781/ https://www.ncbi.nlm.nih.gov/pubmed/21754012 http://dx.doi.org/10.1107/S1600536811010816 |
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author | Hossain, G. M. Golzar |
author_facet | Hossain, G. M. Golzar |
author_sort | Hossain, G. M. Golzar |
collection | PubMed |
description | The complete molecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethylsulfoxide molecules. The resulting N(4)O(2) donor set displays a distorted trigonal–prismatic coordination geometry. The S atom and methyl groups of dimethylsulfoxide are disordered over two sets of sites, with site occupancies of 0.715 (4) and 0.285 (4). The crystal structure features intermolecular N—H⋯N and N—H⋯O hydrogen bonds that lead to the formation of layers in the ab plane. |
format | Text |
id | pubmed-3099781 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30997812011-07-13 cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ(2) N,N′]bis(dimethyl sulfoxide-κO)cadmium Hossain, G. M. Golzar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete molecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethylsulfoxide molecules. The resulting N(4)O(2) donor set displays a distorted trigonal–prismatic coordination geometry. The S atom and methyl groups of dimethylsulfoxide are disordered over two sets of sites, with site occupancies of 0.715 (4) and 0.285 (4). The crystal structure features intermolecular N—H⋯N and N—H⋯O hydrogen bonds that lead to the formation of layers in the ab plane. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099781/ /pubmed/21754012 http://dx.doi.org/10.1107/S1600536811010816 Text en © G. M. Golzar Hossain 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hossain, G. M. Golzar cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ(2) N,N′]bis(dimethyl sulfoxide-κO)cadmium |
title |
cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ(2)
N,N′]bis(dimethyl sulfoxide-κO)cadmium |
title_full |
cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ(2)
N,N′]bis(dimethyl sulfoxide-κO)cadmium |
title_fullStr |
cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ(2)
N,N′]bis(dimethyl sulfoxide-κO)cadmium |
title_full_unstemmed |
cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ(2)
N,N′]bis(dimethyl sulfoxide-κO)cadmium |
title_short |
cis-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamido-κ(2)
N,N′]bis(dimethyl sulfoxide-κO)cadmium |
title_sort | cis-bis[4-amino-n-(pyrimidin-2-yl)benzenesulfonamido-κ(2)
n,n′]bis(dimethyl sulfoxide-κo)cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099781/ https://www.ncbi.nlm.nih.gov/pubmed/21754012 http://dx.doi.org/10.1107/S1600536811010816 |
work_keys_str_mv | AT hossaingmgolzar cisbis4aminonpyrimidin2ylbenzenesulfonamidok2nnbisdimethylsulfoxidekocadmium |