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cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamido-κ(2) N,N′]bis­(dimethyl sulfoxide-κO)cadmium

The complete mol­ecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethyl­sulfoxide mol­ecules. The resulting N(4)O(2) donor set disp...

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Detalles Bibliográficos
Autor principal: Hossain, G. M. Golzar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099781/
https://www.ncbi.nlm.nih.gov/pubmed/21754012
http://dx.doi.org/10.1107/S1600536811010816
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author Hossain, G. M. Golzar
author_facet Hossain, G. M. Golzar
author_sort Hossain, G. M. Golzar
collection PubMed
description The complete mol­ecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethyl­sulfoxide mol­ecules. The resulting N(4)O(2) donor set displays a distorted trigonal–prismatic coordination geometry. The S atom and methyl groups of dimethyl­sulfoxide are disordered over two sets of sites, with site occupancies of 0.715 (4) and 0.285 (4). The crystal structure features inter­molecular N—H⋯N and N—H⋯O hydrogen bonds that lead to the formation of layers in the ab plane.
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spelling pubmed-30997812011-07-13 cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamido-κ(2) N,N′]bis­(dimethyl sulfoxide-κO)cadmium Hossain, G. M. Golzar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete mol­ecule of the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(2)H(6)OS)(2)], is completed by the application of a twofold rotation axis. The Cd(II) atom is six coordinated by two bidentate sulfadiazinate anions and two dimethyl­sulfoxide mol­ecules. The resulting N(4)O(2) donor set displays a distorted trigonal–prismatic coordination geometry. The S atom and methyl groups of dimethyl­sulfoxide are disordered over two sets of sites, with site occupancies of 0.715 (4) and 0.285 (4). The crystal structure features inter­molecular N—H⋯N and N—H⋯O hydrogen bonds that lead to the formation of layers in the ab plane. International Union of Crystallography 2011-03-26 /pmc/articles/PMC3099781/ /pubmed/21754012 http://dx.doi.org/10.1107/S1600536811010816 Text en © G. M. Golzar Hossain 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hossain, G. M. Golzar
cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamido-κ(2) N,N′]bis­(dimethyl sulfoxide-κO)cadmium
title cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamido-κ(2) N,N′]bis­(dimethyl sulfoxide-κO)cadmium
title_full cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamido-κ(2) N,N′]bis­(dimethyl sulfoxide-κO)cadmium
title_fullStr cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamido-κ(2) N,N′]bis­(dimethyl sulfoxide-κO)cadmium
title_full_unstemmed cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamido-κ(2) N,N′]bis­(dimethyl sulfoxide-κO)cadmium
title_short cis-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamido-κ(2) N,N′]bis­(dimethyl sulfoxide-κO)cadmium
title_sort cis-bis[4-amino-n-(pyrimidin-2-yl)benzene­sulfonamido-κ(2) n,n′]bis­(dimethyl sulfoxide-κo)cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099781/
https://www.ncbi.nlm.nih.gov/pubmed/21754012
http://dx.doi.org/10.1107/S1600536811010816
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