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catena-Poly[[bis(2-aminoethanesulfonato-κ(2) N,O)nickel(II)]-μ-1,4-bis(1H-imidazol-1-yl)benzene-κ(2) N (3):N (3′)]
In the hydrothermally prepared title coordination polymer, [Ni(C(2)H(6)NO(3)S)(2)(C(12)H(10)N(4))](n), the Ni(II) ion and the 1,4-bis(1H-imidazol-1-yl)benzene ligand occupy special positions on inversion centers. The metal ion shows a slightly distorted octahedral coordination geometry, being lin...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099785/ https://www.ncbi.nlm.nih.gov/pubmed/21753971 http://dx.doi.org/10.1107/S1600536811009238 |
Sumario: | In the hydrothermally prepared title coordination polymer, [Ni(C(2)H(6)NO(3)S)(2)(C(12)H(10)N(4))](n), the Ni(II) ion and the 1,4-bis(1H-imidazol-1-yl)benzene ligand occupy special positions on inversion centers. The metal ion shows a slightly distorted octahedral coordination geometry, being linked to two N atoms of two 1,4-bis(imidazol-1-yl)benzene ligands and to two O and two N atoms of two chelating 2-aminoethanesulfonate ligands. The 1,4-bis(imidazol-1-yl)benzene ligands bridge symmetry-related Ni(II) ions forming polymeric chains along the [110] direction. |
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