catena-Poly[[bis­(2-amino­ethane­sulfon­ato-κ(2) N,O)nickel(II)]-μ-1,4-bis­(1H-imid­azol-1-yl)benzene-κ(2) N (3):N (3′)]

In the hydro­thermally prepared title coordination polymer, [Ni(C(2)H(6)NO(3)S)(2)(C(12)H(10)N(4))](n), the Ni(II) ion and the 1,4-bis­(1H-imidazol-1-yl)benzene ligand occupy special positions on inversion centers. The metal ion shows a slightly distorted octa­hedral coordination geometry, being lin...

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Detalles Bibliográficos
Autor principal: Liu, Jin-Biao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099785/
https://www.ncbi.nlm.nih.gov/pubmed/21753971
http://dx.doi.org/10.1107/S1600536811009238
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author Liu, Jin-Biao
author_facet Liu, Jin-Biao
author_sort Liu, Jin-Biao
collection PubMed
description In the hydro­thermally prepared title coordination polymer, [Ni(C(2)H(6)NO(3)S)(2)(C(12)H(10)N(4))](n), the Ni(II) ion and the 1,4-bis­(1H-imidazol-1-yl)benzene ligand occupy special positions on inversion centers. The metal ion shows a slightly distorted octa­hedral coordination geometry, being linked to two N atoms of two 1,4-bis­(imidazol-1-yl)benzene ligands and to two O and two N atoms of two chelating 2-amino­ethane­sulfonate ligands. The 1,4-bis­(imidazol-1-yl)benzene ligands bridge symmetry-related Ni(II) ions forming polymeric chains along the [110] direction.
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spelling pubmed-30997852011-07-13 catena-Poly[[bis­(2-amino­ethane­sulfon­ato-κ(2) N,O)nickel(II)]-μ-1,4-bis­(1H-imid­azol-1-yl)benzene-κ(2) N (3):N (3′)] Liu, Jin-Biao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the hydro­thermally prepared title coordination polymer, [Ni(C(2)H(6)NO(3)S)(2)(C(12)H(10)N(4))](n), the Ni(II) ion and the 1,4-bis­(1H-imidazol-1-yl)benzene ligand occupy special positions on inversion centers. The metal ion shows a slightly distorted octa­hedral coordination geometry, being linked to two N atoms of two 1,4-bis­(imidazol-1-yl)benzene ligands and to two O and two N atoms of two chelating 2-amino­ethane­sulfonate ligands. The 1,4-bis­(imidazol-1-yl)benzene ligands bridge symmetry-related Ni(II) ions forming polymeric chains along the [110] direction. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3099785/ /pubmed/21753971 http://dx.doi.org/10.1107/S1600536811009238 Text en © Jin-Biao Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Jin-Biao
catena-Poly[[bis­(2-amino­ethane­sulfon­ato-κ(2) N,O)nickel(II)]-μ-1,4-bis­(1H-imid­azol-1-yl)benzene-κ(2) N (3):N (3′)]
title catena-Poly[[bis­(2-amino­ethane­sulfon­ato-κ(2) N,O)nickel(II)]-μ-1,4-bis­(1H-imid­azol-1-yl)benzene-κ(2) N (3):N (3′)]
title_full catena-Poly[[bis­(2-amino­ethane­sulfon­ato-κ(2) N,O)nickel(II)]-μ-1,4-bis­(1H-imid­azol-1-yl)benzene-κ(2) N (3):N (3′)]
title_fullStr catena-Poly[[bis­(2-amino­ethane­sulfon­ato-κ(2) N,O)nickel(II)]-μ-1,4-bis­(1H-imid­azol-1-yl)benzene-κ(2) N (3):N (3′)]
title_full_unstemmed catena-Poly[[bis­(2-amino­ethane­sulfon­ato-κ(2) N,O)nickel(II)]-μ-1,4-bis­(1H-imid­azol-1-yl)benzene-κ(2) N (3):N (3′)]
title_short catena-Poly[[bis­(2-amino­ethane­sulfon­ato-κ(2) N,O)nickel(II)]-μ-1,4-bis­(1H-imid­azol-1-yl)benzene-κ(2) N (3):N (3′)]
title_sort catena-poly[[bis­(2-amino­ethane­sulfon­ato-κ(2) n,o)nickel(ii)]-μ-1,4-bis­(1h-imid­azol-1-yl)benzene-κ(2) n (3):n (3′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099785/
https://www.ncbi.nlm.nih.gov/pubmed/21753971
http://dx.doi.org/10.1107/S1600536811009238
work_keys_str_mv AT liujinbiao catenapolybis2aminoethanesulfonatok2nonickeliim14bis1himidazol1ylbenzenek2n3n3

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