cyclo-Tri-μ-oxido-tris­{[(η(5),η(5))-1,2-bis­(cyclo­penta­dien­yl)-1,1,2,2-tetra­methyl­disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene

The title compound, [Zr(3)(C(14)H(20)Si(2))(3)O(3)], consists of three disila-bridged zirconocene units, which are connected via an oxide ligand, forming a nearly planar six-membered ring with a maximum displacement of 0.0191 (8) Å. The compound was isolated as a by-product from a mixture of [(C(5)H...

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Detalles Bibliográficos
Autores principales: Arnold, Thomas, Braunschweig, Holger, Gruss, Katrin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099787/
https://www.ncbi.nlm.nih.gov/pubmed/21753927
http://dx.doi.org/10.1107/S1600536811007094
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author Arnold, Thomas
Braunschweig, Holger
Gruss, Katrin
author_facet Arnold, Thomas
Braunschweig, Holger
Gruss, Katrin
author_sort Arnold, Thomas
collection PubMed
description The title compound, [Zr(3)(C(14)H(20)Si(2))(3)O(3)], consists of three disila-bridged zirconocene units, which are connected via an oxide ligand, forming a nearly planar six-membered ring with a maximum displacement of 0.0191 (8) Å. The compound was isolated as a by-product from a mixture of [(C(5)H(4)SiMe(2))(2)ZrCl(2)] and Li[AlH(4)] in Et(2)O.
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spelling pubmed-30997872011-07-13 cyclo-Tri-μ-oxido-tris­{[(η(5),η(5))-1,2-bis­(cyclo­penta­dien­yl)-1,1,2,2-tetra­methyl­disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene Arnold, Thomas Braunschweig, Holger Gruss, Katrin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zr(3)(C(14)H(20)Si(2))(3)O(3)], consists of three disila-bridged zirconocene units, which are connected via an oxide ligand, forming a nearly planar six-membered ring with a maximum displacement of 0.0191 (8) Å. The compound was isolated as a by-product from a mixture of [(C(5)H(4)SiMe(2))(2)ZrCl(2)] and Li[AlH(4)] in Et(2)O. International Union of Crystallography 2011-03-02 /pmc/articles/PMC3099787/ /pubmed/21753927 http://dx.doi.org/10.1107/S1600536811007094 Text en © Arnold et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arnold, Thomas
Braunschweig, Holger
Gruss, Katrin
cyclo-Tri-μ-oxido-tris­{[(η(5),η(5))-1,2-bis­(cyclo­penta­dien­yl)-1,1,2,2-tetra­methyl­disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene
title cyclo-Tri-μ-oxido-tris­{[(η(5),η(5))-1,2-bis­(cyclo­penta­dien­yl)-1,1,2,2-tetra­methyl­disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene
title_full cyclo-Tri-μ-oxido-tris­{[(η(5),η(5))-1,2-bis­(cyclo­penta­dien­yl)-1,1,2,2-tetra­methyl­disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene
title_fullStr cyclo-Tri-μ-oxido-tris­{[(η(5),η(5))-1,2-bis­(cyclo­penta­dien­yl)-1,1,2,2-tetra­methyl­disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene
title_full_unstemmed cyclo-Tri-μ-oxido-tris­{[(η(5),η(5))-1,2-bis­(cyclo­penta­dien­yl)-1,1,2,2-tetra­methyl­disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene
title_short cyclo-Tri-μ-oxido-tris­{[(η(5),η(5))-1,2-bis­(cyclo­penta­dien­yl)-1,1,2,2-tetra­methyl­disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene
title_sort cyclo-tri-μ-oxido-tris­{[(η(5),η(5))-1,2-bis­(cyclo­penta­dien­yl)-1,1,2,2-tetra­methyl­disilane]zirconium(iv)}: a trimeric disila-bridged oxidozirconocene
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099787/
https://www.ncbi.nlm.nih.gov/pubmed/21753927
http://dx.doi.org/10.1107/S1600536811007094
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AT braunschweigholger cyclotrimoxidotrisē5ē512biscyclopentadienyl1122tetramethyldisilanezirconiumivatrimericdisilabridgedoxidozirconocene
AT grusskatrin cyclotrimoxidotrisē5ē512biscyclopentadienyl1122tetramethyldisilanezirconiumivatrimericdisilabridgedoxidozirconocene

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