Poly[aqua(μ-vinyl­phospho­nato)cadmium]

The title compound, [Cd(C(2)H(3)O(3)P)(H(2)O)](n), was obtained from vinyl­phospho­nic acid and cadmium nitrate. The vinyl groups project into the inter­lamellar space and the structure is held together via van der Waals forces. The Cd(2+) ion is six-coordinate and the geometry is best described as...

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Autores principales: Congiardo, Laura K. Byington, Mague, Joel T., Funk, Aaron R., Yngard, Ria, Knight, D. Andrew
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099788/
https://www.ncbi.nlm.nih.gov/pubmed/21753970
http://dx.doi.org/10.1107/S160053681100780X
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author Congiardo, Laura K. Byington
Mague, Joel T.
Funk, Aaron R.
Yngard, Ria
Knight, D. Andrew
author_facet Congiardo, Laura K. Byington
Mague, Joel T.
Funk, Aaron R.
Yngard, Ria
Knight, D. Andrew
author_sort Congiardo, Laura K. Byington
collection PubMed
description The title compound, [Cd(C(2)H(3)O(3)P)(H(2)O)](n), was obtained from vinyl­phospho­nic acid and cadmium nitrate. The vinyl groups project into the inter­lamellar space and the structure is held together via van der Waals forces. The Cd(2+) ion is six-coordinate and the geometry is best described as distorted octa­hedral, with O—Cd—O angles falling within the range 61.72 (13)–101.82 (14)°. Five of the coordinated oxygen atoms originate from the phospho­nate group and the sixth from a bound water molecule. Cd—O distances lie between 2.220 (3) and 2.394 (2) Å. The water mol­ecule is hydrogen bonded to a phospho­nate oxygen atom.
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spelling pubmed-30997882011-07-13 Poly[aqua(μ-vinyl­phospho­nato)cadmium] Congiardo, Laura K. Byington Mague, Joel T. Funk, Aaron R. Yngard, Ria Knight, D. Andrew Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(C(2)H(3)O(3)P)(H(2)O)](n), was obtained from vinyl­phospho­nic acid and cadmium nitrate. The vinyl groups project into the inter­lamellar space and the structure is held together via van der Waals forces. The Cd(2+) ion is six-coordinate and the geometry is best described as distorted octa­hedral, with O—Cd—O angles falling within the range 61.72 (13)–101.82 (14)°. Five of the coordinated oxygen atoms originate from the phospho­nate group and the sixth from a bound water molecule. Cd—O distances lie between 2.220 (3) and 2.394 (2) Å. The water mol­ecule is hydrogen bonded to a phospho­nate oxygen atom. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3099788/ /pubmed/21753970 http://dx.doi.org/10.1107/S160053681100780X Text en © Congiardo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Congiardo, Laura K. Byington
Mague, Joel T.
Funk, Aaron R.
Yngard, Ria
Knight, D. Andrew
Poly[aqua(μ-vinyl­phospho­nato)cadmium]
title Poly[aqua(μ-vinyl­phospho­nato)cadmium]
title_full Poly[aqua(μ-vinyl­phospho­nato)cadmium]
title_fullStr Poly[aqua(μ-vinyl­phospho­nato)cadmium]
title_full_unstemmed Poly[aqua(μ-vinyl­phospho­nato)cadmium]
title_short Poly[aqua(μ-vinyl­phospho­nato)cadmium]
title_sort poly[aqua(μ-vinyl­phospho­nato)cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099788/
https://www.ncbi.nlm.nih.gov/pubmed/21753970
http://dx.doi.org/10.1107/S160053681100780X
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AT maguejoelt polyaquamvinylphosphonatocadmium
AT funkaaronr polyaquamvinylphosphonatocadmium
AT yngardria polyaquamvinylphosphonatocadmium
AT knightdandrew polyaquamvinylphosphonatocadmium

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