Bis(3-hy­droxy­methyl­anilinium) hexa­chloridostannate(IV)

In the title compound, (C(7)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom, located on an inversion center, exists in an octa­hedral coordination environment. The crystal structure exhibits alternating organic and inorganic layers parallel to ([Image: see text]01). The cations and anions are linked via inter...

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Detalles Bibliográficos
Autores principales: Bouacida, Sofiane, Kechout, Habiba, Belhouas, Ratiba, Merazig, Hocine, Roisnel, Thierry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099789/
https://www.ncbi.nlm.nih.gov/pubmed/21753931
http://dx.doi.org/10.1107/S1600536811007252
Descripción
Sumario:In the title compound, (C(7)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom, located on an inversion center, exists in an octa­hedral coordination environment. The crystal structure exhibits alternating organic and inorganic layers parallel to ([Image: see text]01). The cations and anions are linked via inter­molecular N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds. Additional stabilization is provided by π–π stacking inter­actions between the benzene rings of the cations [centroid–centroid distances = 3.6962 (15) and 3.9340 (15) Å].

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