Bis(3-hy­droxy­methyl­anilinium) hexa­chloridostannate(IV)

In the title compound, (C(7)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom, located on an inversion center, exists in an octa­hedral coordination environment. The crystal structure exhibits alternating organic and inorganic layers parallel to ([Image: see text]01). The cations and anions are linked via inter...

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Autores principales: Bouacida, Sofiane, Kechout, Habiba, Belhouas, Ratiba, Merazig, Hocine, Roisnel, Thierry
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099789/
https://www.ncbi.nlm.nih.gov/pubmed/21753931
http://dx.doi.org/10.1107/S1600536811007252
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author Bouacida, Sofiane
Kechout, Habiba
Belhouas, Ratiba
Merazig, Hocine
Roisnel, Thierry
author_facet Bouacida, Sofiane
Kechout, Habiba
Belhouas, Ratiba
Merazig, Hocine
Roisnel, Thierry
author_sort Bouacida, Sofiane
collection PubMed
description In the title compound, (C(7)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom, located on an inversion center, exists in an octa­hedral coordination environment. The crystal structure exhibits alternating organic and inorganic layers parallel to ([Image: see text]01). The cations and anions are linked via inter­molecular N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds. Additional stabilization is provided by π–π stacking inter­actions between the benzene rings of the cations [centroid–centroid distances = 3.6962 (15) and 3.9340 (15) Å].
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spelling pubmed-30997892011-07-13 Bis(3-hy­droxy­methyl­anilinium) hexa­chloridostannate(IV) Bouacida, Sofiane Kechout, Habiba Belhouas, Ratiba Merazig, Hocine Roisnel, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(7)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom, located on an inversion center, exists in an octa­hedral coordination environment. The crystal structure exhibits alternating organic and inorganic layers parallel to ([Image: see text]01). The cations and anions are linked via inter­molecular N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds. Additional stabilization is provided by π–π stacking inter­actions between the benzene rings of the cations [centroid–centroid distances = 3.6962 (15) and 3.9340 (15) Å]. International Union of Crystallography 2011-03-02 /pmc/articles/PMC3099789/ /pubmed/21753931 http://dx.doi.org/10.1107/S1600536811007252 Text en © Bouacida et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bouacida, Sofiane
Kechout, Habiba
Belhouas, Ratiba
Merazig, Hocine
Roisnel, Thierry
Bis(3-hy­droxy­methyl­anilinium) hexa­chloridostannate(IV)
title Bis(3-hy­droxy­methyl­anilinium) hexa­chloridostannate(IV)
title_full Bis(3-hy­droxy­methyl­anilinium) hexa­chloridostannate(IV)
title_fullStr Bis(3-hy­droxy­methyl­anilinium) hexa­chloridostannate(IV)
title_full_unstemmed Bis(3-hy­droxy­methyl­anilinium) hexa­chloridostannate(IV)
title_short Bis(3-hy­droxy­methyl­anilinium) hexa­chloridostannate(IV)
title_sort bis(3-hy­droxy­methyl­anilinium) hexa­chloridostannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099789/
https://www.ncbi.nlm.nih.gov/pubmed/21753931
http://dx.doi.org/10.1107/S1600536811007252
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