2,4,6-Trinitro-N-[4-(phenyl­diazen­yl)phen­yl]aniline

The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl­diazen­yl)aniline (aniline yellow) with picryl­sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl­diazenyl ring system is 6.55 (13)° and that formed by the rings of the picrate–aniline...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099790/
https://www.ncbi.nlm.nih.gov/pubmed/21754214
http://dx.doi.org/10.1107/S160053681101004X
Descripción
Sumario:The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl­diazen­yl)aniline (aniline yellow) with picryl­sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl­diazenyl ring system is 6.55 (13)° and that formed by the rings of the picrate–aniline ring system is 48.76 (12)°. The mol­ecule contains an intra­molecular aniline–nitro N—H⋯O hydrogen bond.

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