2,4,6-Trinitro-N-[4-(phenyl­diazen­yl)phen­yl]aniline

The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl­diazen­yl)aniline (aniline yellow) with picryl­sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl­diazenyl ring system is 6.55 (13)° and that formed by the rings of the picrate–aniline...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099790/
https://www.ncbi.nlm.nih.gov/pubmed/21754214
http://dx.doi.org/10.1107/S160053681101004X
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author Smith, Graham
Wermuth, Urs D.
author_facet Smith, Graham
Wermuth, Urs D.
author_sort Smith, Graham
collection PubMed
description The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl­diazen­yl)aniline (aniline yellow) with picryl­sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl­diazenyl ring system is 6.55 (13)° and that formed by the rings of the picrate–aniline ring system is 48.76 (12)°. The mol­ecule contains an intra­molecular aniline–nitro N—H⋯O hydrogen bond.
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spelling pubmed-30997902011-07-13 2,4,6-Trinitro-N-[4-(phenyl­diazen­yl)phen­yl]aniline Smith, Graham Wermuth, Urs D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(12)N(6)O(6), was prepared from the reaction of 4-(phenyl­diazen­yl)aniline (aniline yellow) with picryl­sulfonic acid. The dihedral angle formed by the two benzene rings of the diphenyl­diazenyl ring system is 6.55 (13)° and that formed by the rings of the picrate–aniline ring system is 48.76 (12)°. The mol­ecule contains an intra­molecular aniline–nitro N—H⋯O hydrogen bond. International Union of Crystallography 2011-03-23 /pmc/articles/PMC3099790/ /pubmed/21754214 http://dx.doi.org/10.1107/S160053681101004X Text en © Smith and Wermuth 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smith, Graham
Wermuth, Urs D.
2,4,6-Trinitro-N-[4-(phenyl­diazen­yl)phen­yl]aniline
title 2,4,6-Trinitro-N-[4-(phenyl­diazen­yl)phen­yl]aniline
title_full 2,4,6-Trinitro-N-[4-(phenyl­diazen­yl)phen­yl]aniline
title_fullStr 2,4,6-Trinitro-N-[4-(phenyl­diazen­yl)phen­yl]aniline
title_full_unstemmed 2,4,6-Trinitro-N-[4-(phenyl­diazen­yl)phen­yl]aniline
title_short 2,4,6-Trinitro-N-[4-(phenyl­diazen­yl)phen­yl]aniline
title_sort 2,4,6-trinitro-n-[4-(phenyl­diazen­yl)phen­yl]aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099790/
https://www.ncbi.nlm.nih.gov/pubmed/21754214
http://dx.doi.org/10.1107/S160053681101004X
work_keys_str_mv AT smithgraham 246trinitron4phenyldiazenylphenylaniline
AT wermuthursd 246trinitron4phenyldiazenylphenylaniline

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