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[N′-(5-Bromo-2-oxidobenzyl­idene-κO)-2-chloro­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxido­vanadium(V)

The V(V) atom in the title complex, [V(C(14)H(8)BrClN(2)O(2))(CH(3)O)O(CH(3)OH)], is six-coordinated by one phenolate O, one imine N and one enolic O atom of the hydrazone ligand, one oxide O atom, one methanol O atom and one methoxide O atom in a distorted octa­hedral geometry. The dihedral angle b...

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Detalles Bibliográficos
Autor principal: Wang, Fu-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099792/
https://www.ncbi.nlm.nih.gov/pubmed/21753958
http://dx.doi.org/10.1107/S1600536811008774
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author Wang, Fu-Ming
author_facet Wang, Fu-Ming
author_sort Wang, Fu-Ming
collection PubMed
description The V(V) atom in the title complex, [V(C(14)H(8)BrClN(2)O(2))(CH(3)O)O(CH(3)OH)], is six-coordinated by one phenolate O, one imine N and one enolic O atom of the hydrazone ligand, one oxide O atom, one methanol O atom and one methoxide O atom in a distorted octa­hedral geometry. The dihedral angle between the two benzene rings of the hydrazone ligand is 13.2 (3)°. The deviation of the V atom towards the oxide O atom from the plane defined by the three donor atoms of the hydrazone ligand and the meth­oxy O atom is 0.318 (2) Å. Bond lengths are comparable with those observed in similar oxidovanadium(V) complexes with hydrazone ligands. In the crystal, pairs of mol­ecules are linked through inter­molecular O—H⋯N hydrogen bonds, forming dimers.
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spelling pubmed-30997922011-07-13 [N′-(5-Bromo-2-oxidobenzyl­idene-κO)-2-chloro­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxido­vanadium(V) Wang, Fu-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The V(V) atom in the title complex, [V(C(14)H(8)BrClN(2)O(2))(CH(3)O)O(CH(3)OH)], is six-coordinated by one phenolate O, one imine N and one enolic O atom of the hydrazone ligand, one oxide O atom, one methanol O atom and one methoxide O atom in a distorted octa­hedral geometry. The dihedral angle between the two benzene rings of the hydrazone ligand is 13.2 (3)°. The deviation of the V atom towards the oxide O atom from the plane defined by the three donor atoms of the hydrazone ligand and the meth­oxy O atom is 0.318 (2) Å. Bond lengths are comparable with those observed in similar oxidovanadium(V) complexes with hydrazone ligands. In the crystal, pairs of mol­ecules are linked through inter­molecular O—H⋯N hydrogen bonds, forming dimers. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3099792/ /pubmed/21753958 http://dx.doi.org/10.1107/S1600536811008774 Text en © Fu-Ming Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Fu-Ming
[N′-(5-Bromo-2-oxidobenzyl­idene-κO)-2-chloro­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxido­vanadium(V)
title [N′-(5-Bromo-2-oxidobenzyl­idene-κO)-2-chloro­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxido­vanadium(V)
title_full [N′-(5-Bromo-2-oxidobenzyl­idene-κO)-2-chloro­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxido­vanadium(V)
title_fullStr [N′-(5-Bromo-2-oxidobenzyl­idene-κO)-2-chloro­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxido­vanadium(V)
title_full_unstemmed [N′-(5-Bromo-2-oxidobenzyl­idene-κO)-2-chloro­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxido­vanadium(V)
title_short [N′-(5-Bromo-2-oxidobenzyl­idene-κO)-2-chloro­benzohydrazidato-κ(2) N′,O](methanol-κO)(methano­lato-κO)oxido­vanadium(V)
title_sort [n′-(5-bromo-2-oxidobenzyl­idene-κo)-2-chloro­benzohydrazidato-κ(2) n′,o](methanol-κo)(methano­lato-κo)oxido­vanadium(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099792/
https://www.ncbi.nlm.nih.gov/pubmed/21753958
http://dx.doi.org/10.1107/S1600536811008774
work_keys_str_mv AT wangfuming n5bromo2oxidobenzylideneko2chlorobenzohydrazidatok2nomethanolkomethanolatokooxidovanadiumv