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[N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ(2) N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
The V(V) atom in the title complex, [V(C(14)H(8)BrClN(2)O(2))(CH(3)O)O(CH(3)OH)], is six-coordinated by one phenolate O, one imine N and one enolic O atom of the hydrazone ligand, one oxide O atom, one methanol O atom and one methoxide O atom in a distorted octahedral geometry. The dihedral angle b...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099792/ https://www.ncbi.nlm.nih.gov/pubmed/21753958 http://dx.doi.org/10.1107/S1600536811008774 |
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author | Wang, Fu-Ming |
author_facet | Wang, Fu-Ming |
author_sort | Wang, Fu-Ming |
collection | PubMed |
description | The V(V) atom in the title complex, [V(C(14)H(8)BrClN(2)O(2))(CH(3)O)O(CH(3)OH)], is six-coordinated by one phenolate O, one imine N and one enolic O atom of the hydrazone ligand, one oxide O atom, one methanol O atom and one methoxide O atom in a distorted octahedral geometry. The dihedral angle between the two benzene rings of the hydrazone ligand is 13.2 (3)°. The deviation of the V atom towards the oxide O atom from the plane defined by the three donor atoms of the hydrazone ligand and the methoxy O atom is 0.318 (2) Å. Bond lengths are comparable with those observed in similar oxidovanadium(V) complexes with hydrazone ligands. In the crystal, pairs of molecules are linked through intermolecular O—H⋯N hydrogen bonds, forming dimers. |
format | Text |
id | pubmed-3099792 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30997922011-07-13 [N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ(2) N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) Wang, Fu-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The V(V) atom in the title complex, [V(C(14)H(8)BrClN(2)O(2))(CH(3)O)O(CH(3)OH)], is six-coordinated by one phenolate O, one imine N and one enolic O atom of the hydrazone ligand, one oxide O atom, one methanol O atom and one methoxide O atom in a distorted octahedral geometry. The dihedral angle between the two benzene rings of the hydrazone ligand is 13.2 (3)°. The deviation of the V atom towards the oxide O atom from the plane defined by the three donor atoms of the hydrazone ligand and the methoxy O atom is 0.318 (2) Å. Bond lengths are comparable with those observed in similar oxidovanadium(V) complexes with hydrazone ligands. In the crystal, pairs of molecules are linked through intermolecular O—H⋯N hydrogen bonds, forming dimers. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3099792/ /pubmed/21753958 http://dx.doi.org/10.1107/S1600536811008774 Text en © Fu-Ming Wang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Fu-Ming [N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ(2) N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title | [N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ(2)
N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title_full | [N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ(2)
N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title_fullStr | [N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ(2)
N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title_full_unstemmed | [N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ(2)
N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title_short | [N′-(5-Bromo-2-oxidobenzylidene-κO)-2-chlorobenzohydrazidato-κ(2)
N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V) |
title_sort | [n′-(5-bromo-2-oxidobenzylidene-κo)-2-chlorobenzohydrazidato-κ(2)
n′,o](methanol-κo)(methanolato-κo)oxidovanadium(v) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099792/ https://www.ncbi.nlm.nih.gov/pubmed/21753958 http://dx.doi.org/10.1107/S1600536811008774 |
work_keys_str_mv | AT wangfuming n5bromo2oxidobenzylideneko2chlorobenzohydrazidatok2nomethanolkomethanolatokooxidovanadiumv |