2-{[(Biphenyl-2-yl)diazen­yl]methyl­idene}-1,3,3-trimethyl­indoline

The title mol­ecule, C(24)H(23)N(3), shows some delocalization of charge based on the small [8.0 (2)°] angle between the indolin-2-yl­idene ring system and the link methyl­diazene C(2)N(2) atom plane. A further twist of 17.2 (3)° is subtended between the C(2)N(2) plane and its attached benzene ring....

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Detalles Bibliográficos
Autores principales: Gainsford, Graeme J., Ashraf, Mohamed, Kay, Andrew J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099795/
https://www.ncbi.nlm.nih.gov/pubmed/21754168
http://dx.doi.org/10.1107/S1600536811008890
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author Gainsford, Graeme J.
Ashraf, Mohamed
Kay, Andrew J.
author_facet Gainsford, Graeme J.
Ashraf, Mohamed
Kay, Andrew J.
author_sort Gainsford, Graeme J.
collection PubMed
description The title mol­ecule, C(24)H(23)N(3), shows some delocalization of charge based on the small [8.0 (2)°] angle between the indolin-2-yl­idene ring system and the link methyl­diazene C(2)N(2) atom plane. A further twist of 17.2 (3)° is subtended between the C(2)N(2) plane and its attached benzene ring. The dihedral angle between the biphenyl rings is 47.96(14)°. In the crystal, the mol­ecules pack via C—H⋯π attractive inter­actions.
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spelling pubmed-30997952011-07-13 2-{[(Biphenyl-2-yl)diazen­yl]methyl­idene}-1,3,3-trimethyl­indoline Gainsford, Graeme J. Ashraf, Mohamed Kay, Andrew J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(24)H(23)N(3), shows some delocalization of charge based on the small [8.0 (2)°] angle between the indolin-2-yl­idene ring system and the link methyl­diazene C(2)N(2) atom plane. A further twist of 17.2 (3)° is subtended between the C(2)N(2) plane and its attached benzene ring. The dihedral angle between the biphenyl rings is 47.96(14)°. In the crystal, the mol­ecules pack via C—H⋯π attractive inter­actions. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3099795/ /pubmed/21754168 http://dx.doi.org/10.1107/S1600536811008890 Text en © Gainsford et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gainsford, Graeme J.
Ashraf, Mohamed
Kay, Andrew J.
2-{[(Biphenyl-2-yl)diazen­yl]methyl­idene}-1,3,3-trimethyl­indoline
title 2-{[(Biphenyl-2-yl)diazen­yl]methyl­idene}-1,3,3-trimethyl­indoline
title_full 2-{[(Biphenyl-2-yl)diazen­yl]methyl­idene}-1,3,3-trimethyl­indoline
title_fullStr 2-{[(Biphenyl-2-yl)diazen­yl]methyl­idene}-1,3,3-trimethyl­indoline
title_full_unstemmed 2-{[(Biphenyl-2-yl)diazen­yl]methyl­idene}-1,3,3-trimethyl­indoline
title_short 2-{[(Biphenyl-2-yl)diazen­yl]methyl­idene}-1,3,3-trimethyl­indoline
title_sort 2-{[(biphenyl-2-yl)diazen­yl]methyl­idene}-1,3,3-trimethyl­indoline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099795/
https://www.ncbi.nlm.nih.gov/pubmed/21754168
http://dx.doi.org/10.1107/S1600536811008890
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AT kayandrewj 2biphenyl2yldiazenylmethylidene133trimethylindoline

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