(2SR,3RS)-Methyl 2-(adamantan-1-yl)-3-phenyl­sulfonyl-3-(pyridin-2-ylsulfan­yl)propano­ate dichloro­methane hemisolvate

The title compound, C(25)H(29)NO(4)S(2) 0.5CH(2)Cl(2), was obtained as a racemate. The pyridine and phenyl rings are arranged face-to-face, giving a weak intra­molecular π–π inter­action [centroid–centroid separation = 3.759 (3) Å]. These inter­actions are extended inter­molecularly, forming chains...

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Detalles Bibliográficos
Autores principales: Meza-León, Rosa-Luisa, Bernès, Sylvain, Ramírez Domínguez, Elsie, Sosa-Rivadeneyra, Martha, Quintero-Cortés, Leticia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099796/
https://www.ncbi.nlm.nih.gov/pubmed/21754240
http://dx.doi.org/10.1107/S1600536811010312
Descripción
Sumario:The title compound, C(25)H(29)NO(4)S(2) 0.5CH(2)Cl(2), was obtained as a racemate. The pyridine and phenyl rings are arranged face-to-face, giving a weak intra­molecular π–π inter­action [centroid–centroid separation = 3.759 (3) Å]. These inter­actions are extended inter­molecularly, forming chains of stacked rings along [001] with separations of 3.859 (3) and 3.916 (3) Å. The solvent used for crystallization, CH(2)Cl(2), is located in voids between the chains of mol­ecules, with a site occupancy of 0.5.

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