Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cobaltate(II) penta­hydrate

In the title compound, (C(6)H(10)N(2))[Co(C(7)H(3)NO(4))(2)]·5H(2)O, the Co(II) ion is six-coordinated in an N(2)O(4) environment by two pyridine-2,6-dicarboxyl­ate (pydc) ligands, having a distorted octa­hedral geometry. The crystal packing is stabilized by inter­molecular N—H⋯O, O—H⋯O and weak C—H...

Descripción completa

Detalles Bibliográficos
Autores principales: Pasdar, Hoda, Sadat Kashani, Saghi, Ghiasi, Reza, Aghabozorg, Hossein, Notash, Behrouz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099797/
https://www.ncbi.nlm.nih.gov/pubmed/21754013
http://dx.doi.org/10.1107/S1600536811009858
Descripción
Sumario:In the title compound, (C(6)H(10)N(2))[Co(C(7)H(3)NO(4))(2)]·5H(2)O, the Co(II) ion is six-coordinated in an N(2)O(4) environment by two pyridine-2,6-dicarboxyl­ate (pydc) ligands, having a distorted octa­hedral geometry. The crystal packing is stabilized by inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds. There are also π–π inter­actions between the pyridine rings of the pydc ligands and between the pydc ligands and the benzene-1,3-diammonium cations, with centroid–centroid distances of 3.4575 (15) and 3.7521 (15) Å.

Ejemplares similares