Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cobaltate(II) penta­hydrate

In the title compound, (C(6)H(10)N(2))[Co(C(7)H(3)NO(4))(2)]·5H(2)O, the Co(II) ion is six-coordinated in an N(2)O(4) environment by two pyridine-2,6-dicarboxyl­ate (pydc) ligands, having a distorted octa­hedral geometry. The crystal packing is stabilized by inter­molecular N—H⋯O, O—H⋯O and weak C—H...

Descripción completa

Detalles Bibliográficos
Autores principales: Pasdar, Hoda, Sadat Kashani, Saghi, Ghiasi, Reza, Aghabozorg, Hossein, Notash, Behrouz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099797/
https://www.ncbi.nlm.nih.gov/pubmed/21754013
http://dx.doi.org/10.1107/S1600536811009858
_version_ 1782204086958948352
author Pasdar, Hoda
Sadat Kashani, Saghi
Ghiasi, Reza
Aghabozorg, Hossein
Notash, Behrouz
author_facet Pasdar, Hoda
Sadat Kashani, Saghi
Ghiasi, Reza
Aghabozorg, Hossein
Notash, Behrouz
author_sort Pasdar, Hoda
collection PubMed
description In the title compound, (C(6)H(10)N(2))[Co(C(7)H(3)NO(4))(2)]·5H(2)O, the Co(II) ion is six-coordinated in an N(2)O(4) environment by two pyridine-2,6-dicarboxyl­ate (pydc) ligands, having a distorted octa­hedral geometry. The crystal packing is stabilized by inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds. There are also π–π inter­actions between the pyridine rings of the pydc ligands and between the pydc ligands and the benzene-1,3-diammonium cations, with centroid–centroid distances of 3.4575 (15) and 3.7521 (15) Å.
format Text
id pubmed-3099797
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30997972011-07-13 Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cobaltate(II) penta­hydrate Pasdar, Hoda Sadat Kashani, Saghi Ghiasi, Reza Aghabozorg, Hossein Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(6)H(10)N(2))[Co(C(7)H(3)NO(4))(2)]·5H(2)O, the Co(II) ion is six-coordinated in an N(2)O(4) environment by two pyridine-2,6-dicarboxyl­ate (pydc) ligands, having a distorted octa­hedral geometry. The crystal packing is stabilized by inter­molecular N—H⋯O, O—H⋯O and weak C—H⋯O hydrogen bonds. There are also π–π inter­actions between the pyridine rings of the pydc ligands and between the pydc ligands and the benzene-1,3-diammonium cations, with centroid–centroid distances of 3.4575 (15) and 3.7521 (15) Å. International Union of Crystallography 2011-03-31 /pmc/articles/PMC3099797/ /pubmed/21754013 http://dx.doi.org/10.1107/S1600536811009858 Text en © Pasdar et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pasdar, Hoda
Sadat Kashani, Saghi
Ghiasi, Reza
Aghabozorg, Hossein
Notash, Behrouz
Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cobaltate(II) penta­hydrate
title Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cobaltate(II) penta­hydrate
title_full Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cobaltate(II) penta­hydrate
title_fullStr Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cobaltate(II) penta­hydrate
title_full_unstemmed Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cobaltate(II) penta­hydrate
title_short Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))cobaltate(II) penta­hydrate
title_sort benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))cobaltate(ii) penta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099797/
https://www.ncbi.nlm.nih.gov/pubmed/21754013
http://dx.doi.org/10.1107/S1600536811009858
work_keys_str_mv AT pasdarhoda benzene13diammoniumbispyridine26dicarboxylatok3o2no6cobaltateiipentahydrate
AT sadatkashanisaghi benzene13diammoniumbispyridine26dicarboxylatok3o2no6cobaltateiipentahydrate
AT ghiasireza benzene13diammoniumbispyridine26dicarboxylatok3o2no6cobaltateiipentahydrate
AT aghabozorghossein benzene13diammoniumbispyridine26dicarboxylatok3o2no6cobaltateiipentahydrate
AT notashbehrouz benzene13diammoniumbispyridine26dicarboxylatok3o2no6cobaltateiipentahydrate

Ejemplares similares