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{4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ(3) S,N,O}(triphenylphosphane-κP)nickel(II)
The Ni(II) atom in the title complex, [Ni(C(13)H(8)BrNOS)(C(18)H(15)P)], is coordinated by the N, O and S atoms of the dianionic tridentate ligand, and its square-planar geometry is completed by a phosphane P atom. The dihedral angle between the aromatic rings in the 4-bromo-2-[(2-sulfidophenyl)im...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099803/ https://www.ncbi.nlm.nih.gov/pubmed/21753963 http://dx.doi.org/10.1107/S1600536811008907 |
| _version_ | 1782204088516083712 |
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| author | Tamizh, M. Muthu Karvembu, R. Varghese, B. Tiekink, Edward R. T. |
| author_facet | Tamizh, M. Muthu Karvembu, R. Varghese, B. Tiekink, Edward R. T. |
| author_sort | Tamizh, M. Muthu |
| collection | PubMed |
| description | The Ni(II) atom in the title complex, [Ni(C(13)H(8)BrNOS)(C(18)H(15)P)], is coordinated by the N, O and S atoms of the dianionic tridentate ligand, and its square-planar geometry is completed by a phosphane P atom. The dihedral angle between the aromatic rings in the 4-bromo-2-[(2-sulfidophenyl)iminomethyl]phenolate ligand is 2.01 (14)°. The most prominent feature of the packing is the presence of supramolecular chains aligned along the a axis, mediated by C—H⋯S interactions. |
| format | Text |
| id | pubmed-3099803 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30998032011-07-13 {4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ(3) S,N,O}(triphenylphosphane-κP)nickel(II) Tamizh, M. Muthu Karvembu, R. Varghese, B. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni(II) atom in the title complex, [Ni(C(13)H(8)BrNOS)(C(18)H(15)P)], is coordinated by the N, O and S atoms of the dianionic tridentate ligand, and its square-planar geometry is completed by a phosphane P atom. The dihedral angle between the aromatic rings in the 4-bromo-2-[(2-sulfidophenyl)iminomethyl]phenolate ligand is 2.01 (14)°. The most prominent feature of the packing is the presence of supramolecular chains aligned along the a axis, mediated by C—H⋯S interactions. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3099803/ /pubmed/21753963 http://dx.doi.org/10.1107/S1600536811008907 Text en © Tamizh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Tamizh, M. Muthu Karvembu, R. Varghese, B. Tiekink, Edward R. T. {4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ(3) S,N,O}(triphenylphosphane-κP)nickel(II) |
| title | {4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ(3)
S,N,O}(triphenylphosphane-κP)nickel(II) |
| title_full | {4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ(3)
S,N,O}(triphenylphosphane-κP)nickel(II) |
| title_fullStr | {4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ(3)
S,N,O}(triphenylphosphane-κP)nickel(II) |
| title_full_unstemmed | {4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ(3)
S,N,O}(triphenylphosphane-κP)nickel(II) |
| title_short | {4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ(3)
S,N,O}(triphenylphosphane-κP)nickel(II) |
| title_sort | {4-bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ(3)
s,n,o}(triphenylphosphane-κp)nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099803/ https://www.ncbi.nlm.nih.gov/pubmed/21753963 http://dx.doi.org/10.1107/S1600536811008907 |
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