Poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate]

In the title compound, {[Cu(C(18)H(12)N(6))]NO(3)·H(2)O}(n), the Cu(I) ion is coordinated by three N atoms [Cu—N 1.962 (3)–2.019 (3) Å] from three 2,4,6-tri-4-pyridyl-1,3,5-triazine (L) ligands. Each L ligand bridges three Cu(I) atoms, generating a positively charged three-dimensional polymeric netw...

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Detalles Bibliográficos
Autores principales: Feng, Miao, Tian, Hui-Juan, Mi, Huai-Feng, Hu, Tong-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099806/
https://www.ncbi.nlm.nih.gov/pubmed/21754019
http://dx.doi.org/10.1107/S1600536811011445
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author Feng, Miao
Tian, Hui-Juan
Mi, Huai-Feng
Hu, Tong-Liang
author_facet Feng, Miao
Tian, Hui-Juan
Mi, Huai-Feng
Hu, Tong-Liang
author_sort Feng, Miao
collection PubMed
description In the title compound, {[Cu(C(18)H(12)N(6))]NO(3)·H(2)O}(n), the Cu(I) ion is coordinated by three N atoms [Cu—N 1.962 (3)–2.019 (3) Å] from three 2,4,6-tri-4-pyridyl-1,3,5-triazine (L) ligands. Each L ligand bridges three Cu(I) atoms, generating a positively charged three-dimensional polymeric network with voids propagated along the b axis. These voids are filled with NO(3) (−) anions with a shortest Cu⋯O distance of 2.645 (3) Å and water mol­ecules, which are linked into negatively charged helical chains via inter­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-30998062011-07-13 Poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate] Feng, Miao Tian, Hui-Juan Mi, Huai-Feng Hu, Tong-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(18)H(12)N(6))]NO(3)·H(2)O}(n), the Cu(I) ion is coordinated by three N atoms [Cu—N 1.962 (3)–2.019 (3) Å] from three 2,4,6-tri-4-pyridyl-1,3,5-triazine (L) ligands. Each L ligand bridges three Cu(I) atoms, generating a positively charged three-dimensional polymeric network with voids propagated along the b axis. These voids are filled with NO(3) (−) anions with a shortest Cu⋯O distance of 2.645 (3) Å and water mol­ecules, which are linked into negatively charged helical chains via inter­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2011-03-31 /pmc/articles/PMC3099806/ /pubmed/21754019 http://dx.doi.org/10.1107/S1600536811011445 Text en © Feng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Feng, Miao
Tian, Hui-Juan
Mi, Huai-Feng
Hu, Tong-Liang
Poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate]
title Poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate]
title_full Poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate]
title_fullStr Poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate]
title_full_unstemmed Poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate]
title_short Poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate]
title_sort poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(i)] nitrate monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099806/
https://www.ncbi.nlm.nih.gov/pubmed/21754019
http://dx.doi.org/10.1107/S1600536811011445
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AT mihuaifeng polym3246tri4pyridyl135triazinecopperinitratemonohydrate
AT hutongliang polym3246tri4pyridyl135triazinecopperinitratemonohydrate

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