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Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ(2) N,O}nickel(II)
In the title complex, [Ni(C(18)H(14)NO)(2)], the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methylphenyl)iminomethyl]-2-naphtholate ligands are coordinated in a trans arrangement with respect to the N and O atoms. In th...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099807/ https://www.ncbi.nlm.nih.gov/pubmed/21753985 http://dx.doi.org/10.1107/S1600536811010087 |
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author | Wang, Quanbo Jiang, Jianzhuang Zhu, Peihua |
author_facet | Wang, Quanbo Jiang, Jianzhuang Zhu, Peihua |
author_sort | Wang, Quanbo |
collection | PubMed |
description | In the title complex, [Ni(C(18)H(14)NO)(2)], the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methylphenyl)iminomethyl]-2-naphtholate ligands are coordinated in a trans arrangement with respect to the N and O atoms. In the symmetry-unique ligand, the dihedral angle between the naphthalene ring system and the benzene ring of the methylphenyl group is 49.03 (7)°. |
format | Text |
id | pubmed-3099807 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30998072011-07-13 Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ(2) N,O}nickel(II) Wang, Quanbo Jiang, Jianzhuang Zhu, Peihua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(18)H(14)NO)(2)], the Ni(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment. The 1-[(4-methylphenyl)iminomethyl]-2-naphtholate ligands are coordinated in a trans arrangement with respect to the N and O atoms. In the symmetry-unique ligand, the dihedral angle between the naphthalene ring system and the benzene ring of the methylphenyl group is 49.03 (7)°. International Union of Crystallography 2011-03-23 /pmc/articles/PMC3099807/ /pubmed/21753985 http://dx.doi.org/10.1107/S1600536811010087 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Quanbo Jiang, Jianzhuang Zhu, Peihua Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ(2) N,O}nickel(II) |
title | Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ(2)
N,O}nickel(II) |
title_full | Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ(2)
N,O}nickel(II) |
title_fullStr | Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ(2)
N,O}nickel(II) |
title_full_unstemmed | Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ(2)
N,O}nickel(II) |
title_short | Bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ(2)
N,O}nickel(II) |
title_sort | bis{1-[(4-methylphenyl)iminomethyl]-2-naphtholato-κ(2)
n,o}nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099807/ https://www.ncbi.nlm.nih.gov/pubmed/21753985 http://dx.doi.org/10.1107/S1600536811010087 |
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