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{4,4′-Dibromo-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II)
In the title compound, [Ni(C(19)H(18)Br(2)N(2)O(2))], the Ni(II) ion, lying on a twofold rotation axis, is coordinated by two N atoms and two O atoms from the Schiff base ligand in a distorted square-planar geometry. Weak intermolecular C—H⋯O hydrogen bonds stabilize the crystal structure.
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099811/ https://www.ncbi.nlm.nih.gov/pubmed/21753968 http://dx.doi.org/10.1107/S1600536811009056 |
| _version_ | 1782204090504183808 |
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| author | Rayati, Saeed Ghaemi, Akbar Notash, Behrouz |
| author_facet | Rayati, Saeed Ghaemi, Akbar Notash, Behrouz |
| author_sort | Rayati, Saeed |
| collection | PubMed |
| description | In the title compound, [Ni(C(19)H(18)Br(2)N(2)O(2))], the Ni(II) ion, lying on a twofold rotation axis, is coordinated by two N atoms and two O atoms from the Schiff base ligand in a distorted square-planar geometry. Weak intermolecular C—H⋯O hydrogen bonds stabilize the crystal structure. |
| format | Text |
| id | pubmed-3099811 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30998112011-07-13 {4,4′-Dibromo-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) Rayati, Saeed Ghaemi, Akbar Notash, Behrouz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(19)H(18)Br(2)N(2)O(2))], the Ni(II) ion, lying on a twofold rotation axis, is coordinated by two N atoms and two O atoms from the Schiff base ligand in a distorted square-planar geometry. Weak intermolecular C—H⋯O hydrogen bonds stabilize the crystal structure. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3099811/ /pubmed/21753968 http://dx.doi.org/10.1107/S1600536811009056 Text en © Rayati et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Rayati, Saeed Ghaemi, Akbar Notash, Behrouz {4,4′-Dibromo-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) |
| title | {4,4′-Dibromo-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_full | {4,4′-Dibromo-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_fullStr | {4,4′-Dibromo-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_full_unstemmed | {4,4′-Dibromo-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_short | {4,4′-Dibromo-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_sort | {4,4′-dibromo-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
o,n,n′,o′}nickel(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099811/ https://www.ncbi.nlm.nih.gov/pubmed/21753968 http://dx.doi.org/10.1107/S1600536811009056 |
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