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3-Chloro-6-[2-(cyclopentylidene)hydrazin-1-yl]pyridazine
The asymmetric unit of the title compound, C(9)H(11)ClN(4), contains two virtually planar molecules that differ in conformation about the bond connecting the hydrazine and pyridazine units. The 3-chloro-6-hydrazinylpyridazine and cyclopentane groups are oriented at dihedral angles of 4.5 (3) and 8...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099815/ https://www.ncbi.nlm.nih.gov/pubmed/21754036 http://dx.doi.org/10.1107/S1600536811011342 |
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author | Ather, Abdul Qayyum Tahir, M. Nawaz Khan, Misbahul Ain Athar, Muhammad Makshoof |
author_facet | Ather, Abdul Qayyum Tahir, M. Nawaz Khan, Misbahul Ain Athar, Muhammad Makshoof |
author_sort | Ather, Abdul Qayyum |
collection | PubMed |
description | The asymmetric unit of the title compound, C(9)H(11)ClN(4), contains two virtually planar molecules that differ in conformation about the bond connecting the hydrazine and pyridazine units. The 3-chloro-6-hydrazinylpyridazine and cyclopentane groups are oriented at dihedral angles of 4.5 (3) and 8.8 (4)° in the two molecules. In the crystal, the molecules form a one dimensional polymeric structure extending along the a axis via N—H⋯N hydrogen bonds. The crystal stucired was an inversion twin [ratio of the twin domains = 0.73 (9):0.27 (9)]. |
format | Text |
id | pubmed-3099815 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30998152011-07-13 3-Chloro-6-[2-(cyclopentylidene)hydrazin-1-yl]pyridazine Ather, Abdul Qayyum Tahir, M. Nawaz Khan, Misbahul Ain Athar, Muhammad Makshoof Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(9)H(11)ClN(4), contains two virtually planar molecules that differ in conformation about the bond connecting the hydrazine and pyridazine units. The 3-chloro-6-hydrazinylpyridazine and cyclopentane groups are oriented at dihedral angles of 4.5 (3) and 8.8 (4)° in the two molecules. In the crystal, the molecules form a one dimensional polymeric structure extending along the a axis via N—H⋯N hydrogen bonds. The crystal stucired was an inversion twin [ratio of the twin domains = 0.73 (9):0.27 (9)]. International Union of Crystallography 2011-03-31 /pmc/articles/PMC3099815/ /pubmed/21754036 http://dx.doi.org/10.1107/S1600536811011342 Text en © Ather et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ather, Abdul Qayyum Tahir, M. Nawaz Khan, Misbahul Ain Athar, Muhammad Makshoof 3-Chloro-6-[2-(cyclopentylidene)hydrazin-1-yl]pyridazine |
title | 3-Chloro-6-[2-(cyclopentylidene)hydrazin-1-yl]pyridazine |
title_full | 3-Chloro-6-[2-(cyclopentylidene)hydrazin-1-yl]pyridazine |
title_fullStr | 3-Chloro-6-[2-(cyclopentylidene)hydrazin-1-yl]pyridazine |
title_full_unstemmed | 3-Chloro-6-[2-(cyclopentylidene)hydrazin-1-yl]pyridazine |
title_short | 3-Chloro-6-[2-(cyclopentylidene)hydrazin-1-yl]pyridazine |
title_sort | 3-chloro-6-[2-(cyclopentylidene)hydrazin-1-yl]pyridazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099815/ https://www.ncbi.nlm.nih.gov/pubmed/21754036 http://dx.doi.org/10.1107/S1600536811011342 |
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