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meso-[5,10,15,20-Tetrakis(4-cyanophenyl)porphyrinato]zinc
In the title compound, [Zn(C(48)H(24)N(8))], the coordination environment of the Zn(2+) ion (site symmetry [Image: see text]) is octahedral, with four indole N atoms forming the equatorial plane and the axial positions being occupied by N atoms from the cyanide groups of neighbouring molecules. In...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099819/ https://www.ncbi.nlm.nih.gov/pubmed/21753956 http://dx.doi.org/10.1107/S160053681100849X |
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author | Dong, Shuai Jiang, Jianzhuang |
author_facet | Dong, Shuai Jiang, Jianzhuang |
author_sort | Dong, Shuai |
collection | PubMed |
description | In the title compound, [Zn(C(48)H(24)N(8))], the coordination environment of the Zn(2+) ion (site symmetry [Image: see text]) is octahedral, with four indole N atoms forming the equatorial plane and the axial positions being occupied by N atoms from the cyanide groups of neighbouring molecules. In the crystal, adjacent molecules are assembled into a two-dimensional supramolecular framework parallel to ([Image: see text]01) via the coodination bonding. Topology analysis reveals this compound to be a (4,4)-connected network. |
format | Text |
id | pubmed-3099819 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30998192011-07-13 meso-[5,10,15,20-Tetrakis(4-cyanophenyl)porphyrinato]zinc Dong, Shuai Jiang, Jianzhuang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(48)H(24)N(8))], the coordination environment of the Zn(2+) ion (site symmetry [Image: see text]) is octahedral, with four indole N atoms forming the equatorial plane and the axial positions being occupied by N atoms from the cyanide groups of neighbouring molecules. In the crystal, adjacent molecules are assembled into a two-dimensional supramolecular framework parallel to ([Image: see text]01) via the coodination bonding. Topology analysis reveals this compound to be a (4,4)-connected network. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3099819/ /pubmed/21753956 http://dx.doi.org/10.1107/S160053681100849X Text en © Dong and Jiang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dong, Shuai Jiang, Jianzhuang meso-[5,10,15,20-Tetrakis(4-cyanophenyl)porphyrinato]zinc |
title |
meso-[5,10,15,20-Tetrakis(4-cyanophenyl)porphyrinato]zinc |
title_full |
meso-[5,10,15,20-Tetrakis(4-cyanophenyl)porphyrinato]zinc |
title_fullStr |
meso-[5,10,15,20-Tetrakis(4-cyanophenyl)porphyrinato]zinc |
title_full_unstemmed |
meso-[5,10,15,20-Tetrakis(4-cyanophenyl)porphyrinato]zinc |
title_short |
meso-[5,10,15,20-Tetrakis(4-cyanophenyl)porphyrinato]zinc |
title_sort | meso-[5,10,15,20-tetrakis(4-cyanophenyl)porphyrinato]zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099819/ https://www.ncbi.nlm.nih.gov/pubmed/21753956 http://dx.doi.org/10.1107/S160053681100849X |
work_keys_str_mv | AT dongshuai meso5101520tetrakis4cyanophenylporphyrinatozinc AT jiangjianzhuang meso5101520tetrakis4cyanophenylporphyrinatozinc |