Bis(η(3)-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(II)

The title compound, [Ni(C(15)H(24)NSi)(2)], is a homoleptic metal–η(3)-aza­allyl centrosymmetric complex containing two aza­allyl ligands bound in an η(3)-manner to an Ni(II) atom located on a center of symmetry. The overall coordination about the Ni(II) atom is square-planar. The C and N atoms of t...

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Detalles Bibliográficos
Autores principales: Hao, Junsheng, Liu, Haimei, Yuan, Hai-Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099823/
https://www.ncbi.nlm.nih.gov/pubmed/21753984
http://dx.doi.org/10.1107/S1600536811009469
Descripción
Sumario:The title compound, [Ni(C(15)H(24)NSi)(2)], is a homoleptic metal–η(3)-aza­allyl centrosymmetric complex containing two aza­allyl ligands bound in an η(3)-manner to an Ni(II) atom located on a center of symmetry. The overall coordination about the Ni(II) atom is square-planar. The C and N atoms of the aza­allyl group are sp (2)-hybridized. The uneven Ni—C and Ni—N distances [2.045 (5)/2.060 (6) and 1.916 (5) Å] are influenced by a steric hindering effect from the nearby benzene ring.

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