Bis(η(3)-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(II)

The title compound, [Ni(C(15)H(24)NSi)(2)], is a homoleptic metal–η(3)-aza­allyl centrosymmetric complex containing two aza­allyl ligands bound in an η(3)-manner to an Ni(II) atom located on a center of symmetry. The overall coordination about the Ni(II) atom is square-planar. The C and N atoms of t...

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Detalles Bibliográficos
Autores principales: Hao, Junsheng, Liu, Haimei, Yuan, Hai-Yan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099823/
https://www.ncbi.nlm.nih.gov/pubmed/21753984
http://dx.doi.org/10.1107/S1600536811009469
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author Hao, Junsheng
Liu, Haimei
Yuan, Hai-Yan
author_facet Hao, Junsheng
Liu, Haimei
Yuan, Hai-Yan
author_sort Hao, Junsheng
collection PubMed
description The title compound, [Ni(C(15)H(24)NSi)(2)], is a homoleptic metal–η(3)-aza­allyl centrosymmetric complex containing two aza­allyl ligands bound in an η(3)-manner to an Ni(II) atom located on a center of symmetry. The overall coordination about the Ni(II) atom is square-planar. The C and N atoms of the aza­allyl group are sp (2)-hybridized. The uneven Ni—C and Ni—N distances [2.045 (5)/2.060 (6) and 1.916 (5) Å] are influenced by a steric hindering effect from the nearby benzene ring.
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spelling pubmed-30998232011-07-13 Bis(η(3)-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(II) Hao, Junsheng Liu, Haimei Yuan, Hai-Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(15)H(24)NSi)(2)], is a homoleptic metal–η(3)-aza­allyl centrosymmetric complex containing two aza­allyl ligands bound in an η(3)-manner to an Ni(II) atom located on a center of symmetry. The overall coordination about the Ni(II) atom is square-planar. The C and N atoms of the aza­allyl group are sp (2)-hybridized. The uneven Ni—C and Ni—N distances [2.045 (5)/2.060 (6) and 1.916 (5) Å] are influenced by a steric hindering effect from the nearby benzene ring. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3099823/ /pubmed/21753984 http://dx.doi.org/10.1107/S1600536811009469 Text en © Hao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hao, Junsheng
Liu, Haimei
Yuan, Hai-Yan
Bis(η(3)-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(II)
title Bis(η(3)-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(II)
title_full Bis(η(3)-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(II)
title_fullStr Bis(η(3)-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(II)
title_full_unstemmed Bis(η(3)-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(II)
title_short Bis(η(3)-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(II)
title_sort bis(η(3)-2-tert-butyl-1-trimethyl­silyl-3-phenyl-1-aza­all­yl)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099823/
https://www.ncbi.nlm.nih.gov/pubmed/21753984
http://dx.doi.org/10.1107/S1600536811009469
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AT liuhaimei bisē32tertbutyl1trimethylsilyl3phenyl1azaallylnickelii
AT yuanhaiyan bisē32tertbutyl1trimethylsilyl3phenyl1azaallylnickelii

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