Diazido­bis­(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)cobalt(II) monohydrate

In the title compound, [Co(C(12)H(12)N(2))(2)(N(3))(2)]·H(2)O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octa­hedral geometry with the two dmbpy (dmbpy = 5,5′-dimethyl-2,2′-bipyrid­yl) and the two azido ligands in a cis arrangement. The solvent water mol­ec...

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Detalles Bibliográficos
Autores principales: Phatchimkun, Jaturong, Chaichit, Narongsak
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099828/
https://www.ncbi.nlm.nih.gov/pubmed/21754020
http://dx.doi.org/10.1107/S1600536811011305
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author Phatchimkun, Jaturong
Chaichit, Narongsak
author_facet Phatchimkun, Jaturong
Chaichit, Narongsak
author_sort Phatchimkun, Jaturong
collection PubMed
description In the title compound, [Co(C(12)H(12)N(2))(2)(N(3))(2)]·H(2)O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octa­hedral geometry with the two dmbpy (dmbpy = 5,5′-dimethyl-2,2′-bipyrid­yl) and the two azido ligands in a cis arrangement. The solvent water mol­ecule and one methyl group of the dmbpy ligand are disordered over two sets of sites in a 1:1 ratio. The crystal structure is stabilized by intra­molecular C—H⋯N(dmbpy) and inter­molecular O—H⋯N(azide) hydrogen bonds.
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spelling pubmed-30998282011-07-13 Diazido­bis­(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)cobalt(II) monohydrate Phatchimkun, Jaturong Chaichit, Narongsak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(12)H(12)N(2))(2)(N(3))(2)]·H(2)O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octa­hedral geometry with the two dmbpy (dmbpy = 5,5′-dimethyl-2,2′-bipyrid­yl) and the two azido ligands in a cis arrangement. The solvent water mol­ecule and one methyl group of the dmbpy ligand are disordered over two sets of sites in a 1:1 ratio. The crystal structure is stabilized by intra­molecular C—H⋯N(dmbpy) and inter­molecular O—H⋯N(azide) hydrogen bonds. International Union of Crystallography 2011-03-31 /pmc/articles/PMC3099828/ /pubmed/21754020 http://dx.doi.org/10.1107/S1600536811011305 Text en © Phatchimkun and Chaichit 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Phatchimkun, Jaturong
Chaichit, Narongsak
Diazido­bis­(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)cobalt(II) monohydrate
title Diazido­bis­(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)cobalt(II) monohydrate
title_full Diazido­bis­(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)cobalt(II) monohydrate
title_fullStr Diazido­bis­(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)cobalt(II) monohydrate
title_full_unstemmed Diazido­bis­(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)cobalt(II) monohydrate
title_short Diazido­bis­(5,5′-dimethyl-2,2′-bipyridyl-κ(2) N,N′)cobalt(II) monohydrate
title_sort diazido­bis­(5,5′-dimethyl-2,2′-bipyridyl-κ(2) n,n′)cobalt(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099828/
https://www.ncbi.nlm.nih.gov/pubmed/21754020
http://dx.doi.org/10.1107/S1600536811011305
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