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Methyl 2-(4-acetamidobenzenesulfonamido)benzoate
The molecule of the title compound, C(16)H(16)N(2)O(5)S, has the shape of the letter V but with a small twist; the dihedral angle formed between the benzene rings is 79.66 (9)°. The presence of an intramolecular N—H⋯O hydrogen bond, leading to an S(6) ring, correlates with the near coplanarity of...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099839/ https://www.ncbi.nlm.nih.gov/pubmed/21754177 http://dx.doi.org/10.1107/S1600536811009500 |
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author | Khan, Islam Ullah Sharif, Shahzad Ali, Salamat Ahmad, Waqar Tiekink, Edward R. T. |
author_facet | Khan, Islam Ullah Sharif, Shahzad Ali, Salamat Ahmad, Waqar Tiekink, Edward R. T. |
author_sort | Khan, Islam Ullah |
collection | PubMed |
description | The molecule of the title compound, C(16)H(16)N(2)O(5)S, has the shape of the letter V but with a small twist; the dihedral angle formed between the benzene rings is 79.66 (9)°. The presence of an intramolecular N—H⋯O hydrogen bond, leading to an S(6) ring, correlates with the near coplanarity of the carboxylate ester group with the benzene ring to which it is connected. The acetamide residue is slightly twisted out of the plane of its benzene ring [C—C—N—C = 13.1 (3)°]. In the crystal, supramolecular chains along the a axis are mediated by N—H⋯O hydrogen bonds. These are connected into layers via C—H⋯O interactions. |
format | Text |
id | pubmed-3099839 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30998392011-07-13 Methyl 2-(4-acetamidobenzenesulfonamido)benzoate Khan, Islam Ullah Sharif, Shahzad Ali, Salamat Ahmad, Waqar Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(16)H(16)N(2)O(5)S, has the shape of the letter V but with a small twist; the dihedral angle formed between the benzene rings is 79.66 (9)°. The presence of an intramolecular N—H⋯O hydrogen bond, leading to an S(6) ring, correlates with the near coplanarity of the carboxylate ester group with the benzene ring to which it is connected. The acetamide residue is slightly twisted out of the plane of its benzene ring [C—C—N—C = 13.1 (3)°]. In the crystal, supramolecular chains along the a axis are mediated by N—H⋯O hydrogen bonds. These are connected into layers via C—H⋯O interactions. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3099839/ /pubmed/21754177 http://dx.doi.org/10.1107/S1600536811009500 Text en © Khan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Khan, Islam Ullah Sharif, Shahzad Ali, Salamat Ahmad, Waqar Tiekink, Edward R. T. Methyl 2-(4-acetamidobenzenesulfonamido)benzoate |
title | Methyl 2-(4-acetamidobenzenesulfonamido)benzoate |
title_full | Methyl 2-(4-acetamidobenzenesulfonamido)benzoate |
title_fullStr | Methyl 2-(4-acetamidobenzenesulfonamido)benzoate |
title_full_unstemmed | Methyl 2-(4-acetamidobenzenesulfonamido)benzoate |
title_short | Methyl 2-(4-acetamidobenzenesulfonamido)benzoate |
title_sort | methyl 2-(4-acetamidobenzenesulfonamido)benzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099839/ https://www.ncbi.nlm.nih.gov/pubmed/21754177 http://dx.doi.org/10.1107/S1600536811009500 |
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