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Methyl 2-(4-acetamido­benzene­sulfon­amido)­benzoate

The mol­ecule of the title compound, C(16)H(16)N(2)O(5)S, has the shape of the letter V but with a small twist; the dihedral angle formed between the benzene rings is 79.66 (9)°. The presence of an intra­molecular N—H⋯O hydrogen bond, leading to an S(6) ring, correlates with the near coplanarity of...

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Autores principales: Khan, Islam Ullah, Sharif, Shahzad, Ali, Salamat, Ahmad, Waqar, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099839/
https://www.ncbi.nlm.nih.gov/pubmed/21754177
http://dx.doi.org/10.1107/S1600536811009500
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author Khan, Islam Ullah
Sharif, Shahzad
Ali, Salamat
Ahmad, Waqar
Tiekink, Edward R. T.
author_facet Khan, Islam Ullah
Sharif, Shahzad
Ali, Salamat
Ahmad, Waqar
Tiekink, Edward R. T.
author_sort Khan, Islam Ullah
collection PubMed
description The mol­ecule of the title compound, C(16)H(16)N(2)O(5)S, has the shape of the letter V but with a small twist; the dihedral angle formed between the benzene rings is 79.66 (9)°. The presence of an intra­molecular N—H⋯O hydrogen bond, leading to an S(6) ring, correlates with the near coplanarity of the carboxyl­ate ester group with the benzene ring to which it is connected. The acetamide residue is slightly twisted out of the plane of its benzene ring [C—C—N—C = 13.1 (3)°]. In the crystal, supra­molecular chains along the a axis are mediated by N—H⋯O hydrogen bonds. These are connected into layers via C—H⋯O inter­actions.
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spelling pubmed-30998392011-07-13 Methyl 2-(4-acetamido­benzene­sulfon­amido)­benzoate Khan, Islam Ullah Sharif, Shahzad Ali, Salamat Ahmad, Waqar Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(16)H(16)N(2)O(5)S, has the shape of the letter V but with a small twist; the dihedral angle formed between the benzene rings is 79.66 (9)°. The presence of an intra­molecular N—H⋯O hydrogen bond, leading to an S(6) ring, correlates with the near coplanarity of the carboxyl­ate ester group with the benzene ring to which it is connected. The acetamide residue is slightly twisted out of the plane of its benzene ring [C—C—N—C = 13.1 (3)°]. In the crystal, supra­molecular chains along the a axis are mediated by N—H⋯O hydrogen bonds. These are connected into layers via C—H⋯O inter­actions. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3099839/ /pubmed/21754177 http://dx.doi.org/10.1107/S1600536811009500 Text en © Khan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khan, Islam Ullah
Sharif, Shahzad
Ali, Salamat
Ahmad, Waqar
Tiekink, Edward R. T.
Methyl 2-(4-acetamido­benzene­sulfon­amido)­benzoate
title Methyl 2-(4-acetamido­benzene­sulfon­amido)­benzoate
title_full Methyl 2-(4-acetamido­benzene­sulfon­amido)­benzoate
title_fullStr Methyl 2-(4-acetamido­benzene­sulfon­amido)­benzoate
title_full_unstemmed Methyl 2-(4-acetamido­benzene­sulfon­amido)­benzoate
title_short Methyl 2-(4-acetamido­benzene­sulfon­amido)­benzoate
title_sort methyl 2-(4-acetamido­benzene­sulfon­amido)­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099839/
https://www.ncbi.nlm.nih.gov/pubmed/21754177
http://dx.doi.org/10.1107/S1600536811009500
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