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Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3) N,N′,N′′]cadmium
In the title compound, [CdBr(2)(C(12)H(19)N(3))], the Cd(II) atom is coordinated by the three N atoms of the (1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine ligand and a bromide ion in the basal plane, and by a second bromide in the apical position. The coordination environment can be descri...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099840/ https://www.ncbi.nlm.nih.gov/pubmed/21753928 http://dx.doi.org/10.1107/S1600536811007033 |
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author | Yin, Run-Ting Cao, Zhe Cheng, Lin |
author_facet | Yin, Run-Ting Cao, Zhe Cheng, Lin |
author_sort | Yin, Run-Ting |
collection | PubMed |
description | In the title compound, [CdBr(2)(C(12)H(19)N(3))], the Cd(II) atom is coordinated by the three N atoms of the (1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine ligand and a bromide ion in the basal plane, and by a second bromide in the apical position. The coordination environment can be described as distorted square pyramidal. The coordination of the enantiopure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enantiomerically pure and corresponds to the S,R,R diastereoisomer. In the crystal, the molecules are linked via weak N—H⋯Br hydrogen bonds into a chain parallel to the b axis. |
format | Text |
id | pubmed-3099840 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30998402011-07-13 Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3) N,N′,N′′]cadmium Yin, Run-Ting Cao, Zhe Cheng, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdBr(2)(C(12)H(19)N(3))], the Cd(II) atom is coordinated by the three N atoms of the (1R,2R)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine ligand and a bromide ion in the basal plane, and by a second bromide in the apical position. The coordination environment can be described as distorted square pyramidal. The coordination of the enantiopure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enantiomerically pure and corresponds to the S,R,R diastereoisomer. In the crystal, the molecules are linked via weak N—H⋯Br hydrogen bonds into a chain parallel to the b axis. International Union of Crystallography 2011-03-02 /pmc/articles/PMC3099840/ /pubmed/21753928 http://dx.doi.org/10.1107/S1600536811007033 Text en © Yin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yin, Run-Ting Cao, Zhe Cheng, Lin Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3) N,N′,N′′]cadmium |
title | Dibromido[(1R,2R,N
(1)
S)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
N,N′,N′′]cadmium |
title_full | Dibromido[(1R,2R,N
(1)
S)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
N,N′,N′′]cadmium |
title_fullStr | Dibromido[(1R,2R,N
(1)
S)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
N,N′,N′′]cadmium |
title_full_unstemmed | Dibromido[(1R,2R,N
(1)
S)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
N,N′,N′′]cadmium |
title_short | Dibromido[(1R,2R,N
(1)
S)-N-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
N,N′,N′′]cadmium |
title_sort | dibromido[(1r,2r,n
(1)
s)-n-(pyridin-2-ylmethyl)cyclohexane-1,2-diamine-κ(3)
n,n′,n′′]cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099840/ https://www.ncbi.nlm.nih.gov/pubmed/21753928 http://dx.doi.org/10.1107/S1600536811007033 |
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