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Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]cadmium

In the title compound, [CdBr(2)(C(12)H(19)N(3))], the Cd(II) atom is coordinated by the three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine ligand and a bromide ion in the basal plane, and by a second bromide in the apical position. The coordination environment can be descri...

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Detalles Bibliográficos
Autores principales: Yin, Run-Ting, Cao, Zhe, Cheng, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099840/
https://www.ncbi.nlm.nih.gov/pubmed/21753928
http://dx.doi.org/10.1107/S1600536811007033
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author Yin, Run-Ting
Cao, Zhe
Cheng, Lin
author_facet Yin, Run-Ting
Cao, Zhe
Cheng, Lin
author_sort Yin, Run-Ting
collection PubMed
description In the title compound, [CdBr(2)(C(12)H(19)N(3))], the Cd(II) atom is coordinated by the three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine ligand and a bromide ion in the basal plane, and by a second bromide in the apical position. The coordination environment can be described as distorted square pyramidal. The coordination of the enanti­o­pure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enanti­omerically pure and corresponds to the S,R,R diastereoisomer. In the crystal, the mol­ecules are linked via weak N—H⋯Br hydrogen bonds into a chain parallel to the b axis.
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spelling pubmed-30998402011-07-13 Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]cadmium Yin, Run-Ting Cao, Zhe Cheng, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdBr(2)(C(12)H(19)N(3))], the Cd(II) atom is coordinated by the three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine ligand and a bromide ion in the basal plane, and by a second bromide in the apical position. The coordination environment can be described as distorted square pyramidal. The coordination of the enanti­o­pure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enanti­omerically pure and corresponds to the S,R,R diastereoisomer. In the crystal, the mol­ecules are linked via weak N—H⋯Br hydrogen bonds into a chain parallel to the b axis. International Union of Crystallography 2011-03-02 /pmc/articles/PMC3099840/ /pubmed/21753928 http://dx.doi.org/10.1107/S1600536811007033 Text en © Yin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yin, Run-Ting
Cao, Zhe
Cheng, Lin
Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]cadmium
title Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]cadmium
title_full Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]cadmium
title_fullStr Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]cadmium
title_full_unstemmed Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]cadmium
title_short Dibromido[(1R,2R,N (1) S)-N-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine-κ(3) N,N′,N′′]cadmium
title_sort dibromido[(1r,2r,n (1) s)-n-(pyridin-2-ylmeth­yl)cyclo­hexane-1,2-diamine-κ(3) n,n′,n′′]cadmium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099840/
https://www.ncbi.nlm.nih.gov/pubmed/21753928
http://dx.doi.org/10.1107/S1600536811007033
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