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(Acetato-κO)bis(1,10-phenanthroline-κ(2) N,N′)copper(II) acetate heptahydrate
In the title complex, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CH(3)CO(2))·7H(2)O, the central Cu(II) ion is five coordinate, being bound to four N atoms from two 1,10-phenanthroline ligands and one O atom from an acetate anion in a strongly distorted square-pyramidal configuration. Hydrogen-bonded water...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099845/ https://www.ncbi.nlm.nih.gov/pubmed/21753980 http://dx.doi.org/10.1107/S1600536811009676 |
| Sumario: | In the title complex, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CH(3)CO(2))·7H(2)O, the central Cu(II) ion is five coordinate, being bound to four N atoms from two 1,10-phenanthroline ligands and one O atom from an acetate anion in a strongly distorted square-pyramidal configuration. Hydrogen-bonded water molecules and an uncoordinated acetate anion form a two-dimensional polymeric structure parallel to (010). The cations are linked to this layer via O—H⋯O hydrogen bonds between one of the water molecules and the coordinated acetate anion. |
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