(Acetato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) acetate hepta­hydrate

In the title complex, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CH(3)CO(2))·7H(2)O, the central Cu(II) ion is five coordinate, being bound to four N atoms from two 1,10-phenanthroline ligands and one O atom from an acetate anion in a strongly distorted square-pyramidal configuration. Hydrogen-bonded water...

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Detalles Bibliográficos
Autores principales: Jing, Buqin, Li, Lianzhi, Dong, Jianfang, Xu, Tao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099845/
https://www.ncbi.nlm.nih.gov/pubmed/21753980
http://dx.doi.org/10.1107/S1600536811009676
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author Jing, Buqin
Li, Lianzhi
Dong, Jianfang
Xu, Tao
author_facet Jing, Buqin
Li, Lianzhi
Dong, Jianfang
Xu, Tao
author_sort Jing, Buqin
collection PubMed
description In the title complex, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CH(3)CO(2))·7H(2)O, the central Cu(II) ion is five coordinate, being bound to four N atoms from two 1,10-phenanthroline ligands and one O atom from an acetate anion in a strongly distorted square-pyramidal configuration. Hydrogen-bonded water mol­ecules and an uncoordinated acetate anion form a two-dimensional polymeric structure parallel to (010). The cations are linked to this layer via O—H⋯O hydrogen bonds between one of the water mol­ecules and the coordinated acetate anion.
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spelling pubmed-30998452011-07-13 (Acetato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) acetate hepta­hydrate Jing, Buqin Li, Lianzhi Dong, Jianfang Xu, Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(CH(3)CO(2))(C(12)H(8)N(2))(2)](CH(3)CO(2))·7H(2)O, the central Cu(II) ion is five coordinate, being bound to four N atoms from two 1,10-phenanthroline ligands and one O atom from an acetate anion in a strongly distorted square-pyramidal configuration. Hydrogen-bonded water mol­ecules and an uncoordinated acetate anion form a two-dimensional polymeric structure parallel to (010). The cations are linked to this layer via O—H⋯O hydrogen bonds between one of the water mol­ecules and the coordinated acetate anion. International Union of Crystallography 2011-03-19 /pmc/articles/PMC3099845/ /pubmed/21753980 http://dx.doi.org/10.1107/S1600536811009676 Text en © Jing et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jing, Buqin
Li, Lianzhi
Dong, Jianfang
Xu, Tao
(Acetato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) acetate hepta­hydrate
title (Acetato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) acetate hepta­hydrate
title_full (Acetato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) acetate hepta­hydrate
title_fullStr (Acetato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) acetate hepta­hydrate
title_full_unstemmed (Acetato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) acetate hepta­hydrate
title_short (Acetato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) acetate hepta­hydrate
title_sort (acetato-κo)bis­(1,10-phenanthroline-κ(2) n,n′)copper(ii) acetate hepta­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099845/
https://www.ncbi.nlm.nih.gov/pubmed/21753980
http://dx.doi.org/10.1107/S1600536811009676
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AT dongjianfang acetatokobis110phenanthrolinek2nncopperiiacetateheptahydrate
AT xutao acetatokobis110phenanthrolinek2nncopperiiacetateheptahydrate

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