2,5-Bis{2,2-bis­[4-(dimethyl­amino)­phen­yl]ethen­yl}-N,N′-diphenyl-N,N′-dipropyl­benzene-1,4-diamine

The title compound, C(60)H(68)N(6), was prepared by Horner olefination of a terephthaldialdehyde and a diaryl­methyl phospho­nate. There is one half-mol­ecule, located on an inversion centre, in the asymmetric unit. The dihedral angle between the plane of the vinyl­ene unit and the central ring is 3...

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Detalles Bibliográficos
Autores principales: Schmitt, Volker, Schollmeyer, Dieter, Detert, Heiner
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099848/
https://www.ncbi.nlm.nih.gov/pubmed/21754153
http://dx.doi.org/10.1107/S160053681100910X
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author Schmitt, Volker
Schollmeyer, Dieter
Detert, Heiner
author_facet Schmitt, Volker
Schollmeyer, Dieter
Detert, Heiner
author_sort Schmitt, Volker
collection PubMed
description The title compound, C(60)H(68)N(6), was prepared by Horner olefination of a terephthaldialdehyde and a diaryl­methyl phospho­nate. There is one half-mol­ecule, located on an inversion centre, in the asymmetric unit. The dihedral angle between the plane of the vinyl­ene unit and the central ring is 36.79 (15)°, while those between the vinyl­ene unit and the lateral phenyl rings are 53.04 (10) and 53.74 (9)°.
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spelling pubmed-30998482011-07-13 2,5-Bis{2,2-bis­[4-(dimethyl­amino)­phen­yl]ethen­yl}-N,N′-diphenyl-N,N′-dipropyl­benzene-1,4-diamine Schmitt, Volker Schollmeyer, Dieter Detert, Heiner Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(60)H(68)N(6), was prepared by Horner olefination of a terephthaldialdehyde and a diaryl­methyl phospho­nate. There is one half-mol­ecule, located on an inversion centre, in the asymmetric unit. The dihedral angle between the plane of the vinyl­ene unit and the central ring is 36.79 (15)°, while those between the vinyl­ene unit and the lateral phenyl rings are 53.04 (10) and 53.74 (9)°. International Union of Crystallography 2011-03-12 /pmc/articles/PMC3099848/ /pubmed/21754153 http://dx.doi.org/10.1107/S160053681100910X Text en © Schmitt et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Schmitt, Volker
Schollmeyer, Dieter
Detert, Heiner
2,5-Bis{2,2-bis­[4-(dimethyl­amino)­phen­yl]ethen­yl}-N,N′-diphenyl-N,N′-dipropyl­benzene-1,4-diamine
title 2,5-Bis{2,2-bis­[4-(dimethyl­amino)­phen­yl]ethen­yl}-N,N′-diphenyl-N,N′-dipropyl­benzene-1,4-diamine
title_full 2,5-Bis{2,2-bis­[4-(dimethyl­amino)­phen­yl]ethen­yl}-N,N′-diphenyl-N,N′-dipropyl­benzene-1,4-diamine
title_fullStr 2,5-Bis{2,2-bis­[4-(dimethyl­amino)­phen­yl]ethen­yl}-N,N′-diphenyl-N,N′-dipropyl­benzene-1,4-diamine
title_full_unstemmed 2,5-Bis{2,2-bis­[4-(dimethyl­amino)­phen­yl]ethen­yl}-N,N′-diphenyl-N,N′-dipropyl­benzene-1,4-diamine
title_short 2,5-Bis{2,2-bis­[4-(dimethyl­amino)­phen­yl]ethen­yl}-N,N′-diphenyl-N,N′-dipropyl­benzene-1,4-diamine
title_sort 2,5-bis{2,2-bis­[4-(dimethyl­amino)­phen­yl]ethen­yl}-n,n′-diphenyl-n,n′-dipropyl­benzene-1,4-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099848/
https://www.ncbi.nlm.nih.gov/pubmed/21754153
http://dx.doi.org/10.1107/S160053681100910X
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AT schollmeyerdieter 25bis22bis4dimethylaminophenylethenylnndiphenylnndipropylbenzene14diamine
AT detertheiner 25bis22bis4dimethylaminophenylethenylnndiphenylnndipropylbenzene14diamine

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