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[1,2-Bis(diphenylphosphanyl)ethane-κ(2) P,P′]{2-[(4-nitrobenzoylmethyl)diphenylphosphanyl]phenyl-κ(2) C,C′}palladium(II) trifluoromethanesulfonate–dichloromethane–n-hexane (1/1/0.5)
In the cation of the title compound, [Pd(C(26)H(19)NO(3)P)(C(26)H(24)P(2))]CF(3)O(3)S·CH(2)Cl(2)·0.5C(6)H(14), the Pd(II) atom has a slightly tetrahedrally distorted square-planar coordination geometry. The PdC(3)P and PdC(2)P(2) five-membered metallacycles adopt envelope and twist conformations, r...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099852/ https://www.ncbi.nlm.nih.gov/pubmed/21753947 http://dx.doi.org/10.1107/S1600536811008075 |
Sumario: | In the cation of the title compound, [Pd(C(26)H(19)NO(3)P)(C(26)H(24)P(2))]CF(3)O(3)S·CH(2)Cl(2)·0.5C(6)H(14), the Pd(II) atom has a slightly tetrahedrally distorted square-planar coordination geometry. The PdC(3)P and PdC(2)P(2) five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, intermolecular C—H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dichloromethane solvent molecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent molecule has a crystallographically imposed centre of symmetry. |
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