[1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ(2) C,C′}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)

In the cation of the title compound, [Pd(C(26)H(19)NO(3)P)(C(26)H(24)P(2))]CF(3)O(3)S·CH(2)Cl(2)·0.5C(6)H(14), the Pd(II) atom has a slightly tetra­hedrally distorted square-planar coordination geometry. The PdC(3)P and PdC(2)P(2) five-membered metallacycles adopt envelope and twist conformations, r...

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Detalles Bibliográficos
Autores principales: Rizzoli, Corrado, Karami, Kazem, Borzooie, Farzaneh
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099852/
https://www.ncbi.nlm.nih.gov/pubmed/21753947
http://dx.doi.org/10.1107/S1600536811008075
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author Rizzoli, Corrado
Karami, Kazem
Borzooie, Farzaneh
author_facet Rizzoli, Corrado
Karami, Kazem
Borzooie, Farzaneh
author_sort Rizzoli, Corrado
collection PubMed
description In the cation of the title compound, [Pd(C(26)H(19)NO(3)P)(C(26)H(24)P(2))]CF(3)O(3)S·CH(2)Cl(2)·0.5C(6)H(14), the Pd(II) atom has a slightly tetra­hedrally distorted square-planar coordination geometry. The PdC(3)P and PdC(2)P(2) five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, inter­molecular C—H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dichloro­methane solvent mol­ecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent mol­ecule has a crystallographically imposed centre of symmetry.
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spelling pubmed-30998522011-07-13 [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ(2) C,C′}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5) Rizzoli, Corrado Karami, Kazem Borzooie, Farzaneh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the cation of the title compound, [Pd(C(26)H(19)NO(3)P)(C(26)H(24)P(2))]CF(3)O(3)S·CH(2)Cl(2)·0.5C(6)H(14), the Pd(II) atom has a slightly tetra­hedrally distorted square-planar coordination geometry. The PdC(3)P and PdC(2)P(2) five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, inter­molecular C—H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dichloro­methane solvent mol­ecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent mol­ecule has a crystallographically imposed centre of symmetry. International Union of Crystallography 2011-03-09 /pmc/articles/PMC3099852/ /pubmed/21753947 http://dx.doi.org/10.1107/S1600536811008075 Text en © Rizzoli et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rizzoli, Corrado
Karami, Kazem
Borzooie, Farzaneh
[1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ(2) C,C′}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)
title [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ(2) C,C′}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)
title_full [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ(2) C,C′}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)
title_fullStr [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ(2) C,C′}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)
title_full_unstemmed [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ(2) C,C′}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)
title_short [1,2-Bis(diphenyl­phosphan­yl)ethane-κ(2) P,P′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ(2) C,C′}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)
title_sort [1,2-bis(diphenyl­phosphan­yl)ethane-κ(2) p,p′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ(2) c,c′}palladium(ii) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099852/
https://www.ncbi.nlm.nih.gov/pubmed/21753947
http://dx.doi.org/10.1107/S1600536811008075
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AT karamikazem 12bisdiphenylphosphanylethanek2pp24nitrobenzoylmethyldiphenylphosphanylphenylk2ccpalladiumiitrifluoromethanesulfonatedichloromethanenhexane1105
AT borzooiefarzaneh 12bisdiphenylphosphanylethanek2pp24nitrobenzoylmethyldiphenylphosphanylphenylk2ccpalladiumiitrifluoromethanesulfonatedichloromethanenhexane1105

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