(5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)nickel(II) trihydrate

The Ni(II) atom in the title compound, [Ni(C(8)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)(3)]·3H(2)O, is six-coordinated in an NiN(3)O(3) octa­hedral geometry. The triply water-coordinated Ni(II) atom is chelated by the phenantroline ligand and is additionally coordinated by the amino group of the 5-amino­iso...

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Detalles Bibliográficos
Autores principales: Huang, Han, Zhang, Kou-Lin, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099854/
https://www.ncbi.nlm.nih.gov/pubmed/21753965
http://dx.doi.org/10.1107/S1600536811008919
Descripción
Sumario:The Ni(II) atom in the title compound, [Ni(C(8)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)(3)]·3H(2)O, is six-coordinated in an NiN(3)O(3) octa­hedral geometry. The triply water-coordinated Ni(II) atom is chelated by the phenantroline ligand and is additionally coordinated by the amino group of the 5-amino­isophtalate anion. The anion, the coordinated and the uncoordinated water mol­ecules inter­act through an extensive O—H⋯O and N—H⋯O hydrogen-bonding network, generating a three-dimensional cage-like network.

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