(5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)nickel(II) trihydrate

The Ni(II) atom in the title compound, [Ni(C(8)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)(3)]·3H(2)O, is six-coordinated in an NiN(3)O(3) octa­hedral geometry. The triply water-coordinated Ni(II) atom is chelated by the phenantroline ligand and is additionally coordinated by the amino group of the 5-amino­iso...

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Detalles Bibliográficos
Autores principales: Huang, Han, Zhang, Kou-Lin, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099854/
https://www.ncbi.nlm.nih.gov/pubmed/21753965
http://dx.doi.org/10.1107/S1600536811008919
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author Huang, Han
Zhang, Kou-Lin
Ng, Seik Weng
author_facet Huang, Han
Zhang, Kou-Lin
Ng, Seik Weng
author_sort Huang, Han
collection PubMed
description The Ni(II) atom in the title compound, [Ni(C(8)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)(3)]·3H(2)O, is six-coordinated in an NiN(3)O(3) octa­hedral geometry. The triply water-coordinated Ni(II) atom is chelated by the phenantroline ligand and is additionally coordinated by the amino group of the 5-amino­isophtalate anion. The anion, the coordinated and the uncoordinated water mol­ecules inter­act through an extensive O—H⋯O and N—H⋯O hydrogen-bonding network, generating a three-dimensional cage-like network.
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spelling pubmed-30998542011-07-13 (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)nickel(II) trihydrate Huang, Han Zhang, Kou-Lin Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni(II) atom in the title compound, [Ni(C(8)H(5)NO(4))(C(12)H(8)N(2))(H(2)O)(3)]·3H(2)O, is six-coordinated in an NiN(3)O(3) octa­hedral geometry. The triply water-coordinated Ni(II) atom is chelated by the phenantroline ligand and is additionally coordinated by the amino group of the 5-amino­isophtalate anion. The anion, the coordinated and the uncoordinated water mol­ecules inter­act through an extensive O—H⋯O and N—H⋯O hydrogen-bonding network, generating a three-dimensional cage-like network. International Union of Crystallography 2011-03-15 /pmc/articles/PMC3099854/ /pubmed/21753965 http://dx.doi.org/10.1107/S1600536811008919 Text en © Huang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Han
Zhang, Kou-Lin
Ng, Seik Weng
(5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)nickel(II) trihydrate
title (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)nickel(II) trihydrate
title_full (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)nickel(II) trihydrate
title_fullStr (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)nickel(II) trihydrate
title_full_unstemmed (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)nickel(II) trihydrate
title_short (5-Amino­isophthalato-κN)triaqua­(1,10-phenanthroline-κ(2) N,N′)nickel(II) trihydrate
title_sort (5-amino­isophthalato-κn)triaqua­(1,10-phenanthroline-κ(2) n,n′)nickel(ii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099854/
https://www.ncbi.nlm.nih.gov/pubmed/21753965
http://dx.doi.org/10.1107/S1600536811008919
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AT zhangkoulin 5aminoisophthalatokntriaqua110phenanthrolinek2nnnickeliitrihydrate
AT ngseikweng 5aminoisophthalatokntriaqua110phenanthrolinek2nnnickeliitrihydrate

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