The one-dimensional organic–inorganic hybrid: catena-poly[bis­[1-(3-ammonio­prop­yl)-1H-imidazolium] [[iodidoplumbate(II)]-tri-μ-iodido-plumbate(II)-tri-μ-iodido-[iodidoplumbate(II)]-di-μ-iodido]]

The organic–inorganic hybrid, {(C(6)H(13)N(3))(2)[Pb(3)I(10)]}(n), was obtained by the reaction of 1-(3-ammonio­prop­yl)imidazolium triiodide and PbI(2) at room temperature. The structure contains one-dimensional {[Pb(3)I(10)](4−)}(n) polymeric anions spreading parallel to [001], resulting from face...

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Detalles Bibliográficos
Autores principales: Trigui, A., Boughzala, H., Driss, A., Abid, Y.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099864/
https://www.ncbi.nlm.nih.gov/pubmed/21753976
http://dx.doi.org/10.1107/S160053681100941X
Descripción
Sumario:The organic–inorganic hybrid, {(C(6)H(13)N(3))(2)[Pb(3)I(10)]}(n), was obtained by the reaction of 1-(3-ammonio­prop­yl)imidazolium triiodide and PbI(2) at room temperature. The structure contains one-dimensional {[Pb(3)I(10)](4−)}(n) polymeric anions spreading parallel to [001], resulting from face–face–edge association of PbI(6) distorted octa­hedra. One of the Pb(II) cations is imposed at an inversion centre, whereas the second occupies a general position. N—H⋯I hydrogen bonds connect the organic cations and inorganic anions.

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