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Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ(2) N:N′]dimolybdenum(II) tetrahydrofuran solvate
The title complex, [Mo(2)(C(13)H(9)N(2)Br(2))(4)]·C(4)H(8)O, contains a quadruply bonded Mo(2) (4+) unit equatorially coordinated by four N,N′-bis(4-bromophenyl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo—Mo bond is located on a special position with 2/m s...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099865/ https://www.ncbi.nlm.nih.gov/pubmed/21754018 http://dx.doi.org/10.1107/S1600536811011202 |
Sumario: | The title complex, [Mo(2)(C(13)H(9)N(2)Br(2))(4)]·C(4)H(8)O, contains a quadruply bonded Mo(2) (4+) unit equatorially coordinated by four N,N′-bis(4-bromophenyl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo—Mo bond is located on a special position with 2/m symmetry. In the crystal, complex molecules are linked by Br⋯Br interactions [3.7049 (10) Å]. The disordered solvent molecule could not be satisfactorily modelled and was therefore eliminated from the final refinement. |
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