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Tetra­kis[μ-N,N′-bis­(4-bromo­phen­yl)formamidinato-κ(2) N:N′]dimolyb­denum(II) tetra­hydro­furan solvate

The title complex, [Mo(2)(C(13)H(9)N(2)Br(2))(4)]·C(4)H(8)O, contains a quadruply bonded Mo(2) (4+) unit equatorially coordinated by four N,N′-bis­(4-bromo­phen­yl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo—Mo bond is located on a special position with 2/m s...

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Detalles Bibliográficos
Autor principal: Han, L.-J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099865/
https://www.ncbi.nlm.nih.gov/pubmed/21754018
http://dx.doi.org/10.1107/S1600536811011202
Descripción
Sumario:The title complex, [Mo(2)(C(13)H(9)N(2)Br(2))(4)]·C(4)H(8)O, contains a quadruply bonded Mo(2) (4+) unit equatorially coordinated by four N,N′-bis­(4-bromo­phen­yl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo—Mo bond is located on a special position with 2/m symmetry. In the crystal, complex mol­ecules are linked by Br⋯Br inter­actions [3.7049 (10) Å]. The disordered solvent mol­ecule could not be satisfactorily modelled and was therefore eliminated from the final refinement.