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Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ(2) N:N′]dimolybdenum(II) tetrahydrofuran solvate
The title complex, [Mo(2)(C(13)H(9)N(2)Br(2))(4)]·C(4)H(8)O, contains a quadruply bonded Mo(2) (4+) unit equatorially coordinated by four N,N′-bis(4-bromophenyl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo—Mo bond is located on a special position with 2/m s...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099865/ https://www.ncbi.nlm.nih.gov/pubmed/21754018 http://dx.doi.org/10.1107/S1600536811011202 |
| _version_ | 1782204103353434112 |
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| author | Han, L.-J. |
| author_facet | Han, L.-J. |
| author_sort | Han, L.-J. |
| collection | PubMed |
| description | The title complex, [Mo(2)(C(13)H(9)N(2)Br(2))(4)]·C(4)H(8)O, contains a quadruply bonded Mo(2) (4+) unit equatorially coordinated by four N,N′-bis(4-bromophenyl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo—Mo bond is located on a special position with 2/m symmetry. In the crystal, complex molecules are linked by Br⋯Br interactions [3.7049 (10) Å]. The disordered solvent molecule could not be satisfactorily modelled and was therefore eliminated from the final refinement. |
| format | Text |
| id | pubmed-3099865 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30998652011-07-13 Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ(2) N:N′]dimolybdenum(II) tetrahydrofuran solvate Han, L.-J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Mo(2)(C(13)H(9)N(2)Br(2))(4)]·C(4)H(8)O, contains a quadruply bonded Mo(2) (4+) unit equatorially coordinated by four N,N′-bis(4-bromophenyl)formamidinate ligands, forming a dimetal paddlewheel complex. The centroid of the Mo—Mo bond is located on a special position with 2/m symmetry. In the crystal, complex molecules are linked by Br⋯Br interactions [3.7049 (10) Å]. The disordered solvent molecule could not be satisfactorily modelled and was therefore eliminated from the final refinement. International Union of Crystallography 2011-03-31 /pmc/articles/PMC3099865/ /pubmed/21754018 http://dx.doi.org/10.1107/S1600536811011202 Text en © L.-J. Han 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Han, L.-J. Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ(2) N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title | Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ(2)
N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title_full | Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ(2)
N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title_fullStr | Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ(2)
N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title_full_unstemmed | Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ(2)
N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title_short | Tetrakis[μ-N,N′-bis(4-bromophenyl)formamidinato-κ(2)
N:N′]dimolybdenum(II) tetrahydrofuran solvate |
| title_sort | tetrakis[μ-n,n′-bis(4-bromophenyl)formamidinato-κ(2)
n:n′]dimolybdenum(ii) tetrahydrofuran solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3099865/ https://www.ncbi.nlm.nih.gov/pubmed/21754018 http://dx.doi.org/10.1107/S1600536811011202 |
| work_keys_str_mv | AT hanlj tetrakismnnbis4bromophenylformamidinatok2nndimolybdenumiitetrahydrofuransolvate |